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| 中文名 | 三羰基环己二烯基铁 |
|---|---|
| 英文名 | (Cyclohexadiene)iron tricarbonyl, 97+% |
| 中文别名 | 环己二烯三羰基铁 |
| 英文别名 |
MFCD00070435
Cyclohexadieneirontricarbonylorangeyellowliq Tricarbonylcyclohexadiene iron 1,3-cyclohexadienetricarbonyliron (cyclohexa-1,3-diene)iron tricarbonyl CYCLOHEXADIENE IRON TRICARBONYL |
| 熔点 | 8ºC |
|---|---|
| 分子式 | C9H8FeO3 |
| 分子量 | 220.00300 |
| 精确质量 | 219.98200 |
| LogP | 1.26610 |
| 储存条件 | 常温密闭避光，通风干燥处 |
| 稳定性 | 常温常压下稳定 避免的物料 氧化物 卤素 空气热 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：219.982286 Da 8、标称质量：220 Da 9、平均质量：220.003 Da |
| 更多 | 1. 性状：黄色液体 2. 密度（g/mL, 20 ℃ ）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：8 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC，1mmHg）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（20ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:Cyclohexadiene iron tricarbonyl, 98% CAS Registry Number:12152-72-6 Formula:C6H8Fe(CO)3 EINECS Number:None Chemical Family:metal carbonyl complexes Synonym:1,4-Cyclohexadiene iron tricarbonyl
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound12152-72-6100%no datano data Section 3: Hazards Identification Harmful by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory Emergency Overview: tract. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes. Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Harmful in contact with skin. Inhalation:Harmful by inhalation. may be irritating to the nose, mucous membranes and respiratory tract. Ingestion:harmful if swallowed. Acute Health Affects:Harmful by inhalation, in contact with skin and if swallowed. The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards Chronic Health Affects: may be present. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container. Prolonged exposure to the air will result in degradation of the Handling and Storage: product. Handle and store material under an inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow to orange liq. Molecular Weight:220.01 Melting Point:8° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Contact with air Incompatibility:Oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and iron oxide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable liquids, N.O.S. Hazard Class (CFR):3 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1993 Shipping Name (IATA):Flammable liquids, N.O.S. Hazard Class (IATA):3 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1993 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜 在眼睛上面：刺激的影响 致敏作用：没有已知的敏化现象 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。
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| 风险声明 (欧洲) | 11-36/37/38 |
|---|---|
| 安全声明 (欧洲) | 16-26-36 |
| 危险品运输编码 | UN 1993 |
| 包装等级 | II |
| 危险类别 | 6.1 |