102-86-3

• 常用中文名：三己胺
• 常用英文名：Tri-N-hexylamine
• CAS号：102-86-3
• 分子式：C₁₈H₃₉N
• 分子量：269.50900
• 发布时间：2018-08-23 20:52:28
• 更新时间：2024-01-02 12:41:28

• 用作溶剂、有机合成中间体。

名称

• 中文名: 三己胺
• 英文名: tri-n-hexylamine
• 中文别名: 三正己胺
• 英文别名: 1,1',1''-Nitrilotrihexane; TrihexylaMine; N-TRIHEXYLAMINE; Tri-N-Hexylamine; n,n-dihexyl-1-hexanamin; tri-n-hexyl amine; 1-Hexanamine,N,N-dihexyl; EINECS 203-062-9; MFCD00009523

物化性质

• 密度: 0.794 g/mL at 25 °C(lit.)
• 沸点: 150-159 °C12 mm Hg(lit.)
• 熔点: <-75ºC
• 分子式: C₁₈H₃₉N
• 分子量: 269.50900
• 闪点: >230 °F
• 精确质量: 269.30800
• PSA: 3.24000
• LogP: 6.02930
• 外观性状: 无色至淡黄色液体
• 蒸汽密度: 9.3 (vs air)
• 蒸汽压: 0.0103mmHg at 25°C
• 折射率: n20/D 1.442(lit.)
• 储存条件:

  储存于阴凉、通风的库房。远离火种、热源。应与氧化剂、酸性物质等分开存放，切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。

• 稳定性:

  避免与强氧化剂、酸接触。使用时应穿防护服。

• 分子结构:

  1、 摩尔折射率：89.16

  2、 摩尔体积（cm³/mol）：332.9

  3、 等张比容（90.2K）：733.9

  4、 表面张力（dyne/cm）：29.2

  5、 介电常数：

  6、 偶极距（10^-24cm³）：

  7、 极化率：35.34
• 计算化学:

  1.疏水参数计算参考值（XlogP）:7.3

  2.氢键供体数量:0

  3.氢键受体数量:1

  4.可旋转化学键数量:15

  5.互变异构体数量:无

  6.拓扑分子极性表面积3.2

  7.重原子数量:19

  8.表面电荷:0

  9.复杂度:127

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无色液体，类似胺气味。

  2. 密度（g/mL,20/4℃）：0.798

  3. 相对蒸汽密度（g/mL,空气=1）：9.3

  4. 熔点（ºC）：<-75

  5. 沸点（ºC,常压）：163~265

  6. 沸点（ºC,1.6KPa）：150~159

  7. 折射率（20ºC）：1.442

  8. 闪点（ºC）：144

  9. 自燃点或引燃温度（ºC）：230

  10. 蒸气压（mmHg,20ºC）：<1

  11. 爆炸上限（%,V/V）：2.4

  12. 爆炸下限（%,V/V）：0.2

  13. 溶解性：易溶于乙醇、乙醚，能溶于酸，微溶于水。

MSDS

Name: Trihexylamine 98% Material Safety Data Sheet Synonym: CAS: 102-86-3 Section 1 - Chemical Product MSDS Name:Trihexylamine 98% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 102-86-3 Trihexylamine 98% 203-062-9 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 102-86-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear, colorless Odor: Not available. pH: Not available. Vapor Pressure: < 1 mm Hg @ 20 deg Viscosity: Not available. Boiling Point: 263 - 265 deg C @ 760.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 112 deg C (> 233.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .7984g/cm3 Molecular Formula: C18H39N Molecular Weight: 269.51 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 102-86-3 unlisted. LD50/LC50: Not available. Carcinogenicity: Trihexylamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.* Hazard Class: 8 UN Number: 2735 Packing Group: III IMO Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing Group: III RID/ADR Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 102-86-3: No information available. Canada CAS# 102-86-3 is listed on Canada's DSL List. CAS# 102-86-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 102-86-3 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1、 急性毒性：大鼠经口LD50：1150mg/kg 2、口服有毒。对眼睛、呼吸系统及皮肤有刺激性。 生态学数据: 该物质对环境有危害，应特别注意对水体的污染。对水生物有毒。能对水环境引起不利的结果。

安全

• 符号: GHS07, GHS09
• 信号词: Warning
• 危害声明: H302-H315-H319-H335-H411
• 警示性声明: P261-P273-P305 + P351 + P338
• 个人防护装备: Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R22;R34;R51/53
• 安全声明 (欧洲): S26-S36-S61
• 危险品运输编码: UN 3082 9/PG 3
• WGK德国: 3
• 包装等级: III
• 危险类别: 9
• 海关编码: 2921199090

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海关

海关编码	2921199090
中文概述	2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%