66339-00-2

• 常用中文名：ethyl (Z)-alpha-(hydroxyimino)-2-(tritylamino)thiazol-4-acetate hydrochloride
• 常用英文名：ethyl (Z)-alpha-(hydroxyimino)-2-(tritylamino)thiazol-4-acetate hydrochloride
• CAS号：66339-00-2
• 分子式：C₂₆H₂₄ClN₃O₃S
• 分子量：494.00500
• 发布时间：2017-08-03 09:52:51
• 更新时间：2024-02-01 10:05:01

名称

• 英文名: ethyl (Z)-α-(hydroxyimino)-2-(tritylamino)thiazol-4-acetate hydrochloride
• 英文别名: 4-Thiazoleacetic acid,a-(hydroxyiMino)-2-[(triphenylMethyl)aMino]-,ethyl ester,Monohydrochloride,(Z); ETHYL 2-(HYDROXYIMINO)-2-[2-(TRITYLAMINO)THIAZOL-4-YL]ACETATE HYDROCHLORIDE; ethyl (Z)-2-hydroxyimino-2-(2-tritylaminothiazol-4-yl)-acetate hydrochloride; chlorhydrate d'hydroxyimino-2 Z (tritylamino-2 thiazolyl-4)-2 acetate d'ethyle; ethyl (Z)-2-(2-triphenylmethylaminothiazol-4-yl)-2-(hydroxyimino)acetate hydrochloride; Ethyl (Z)-2-hydroxyimino-2-(2-triphenylmethylaminothiazol-4-yl) acetate hydrochloride; ethyl 2-(2-tritylamino-4-thiazolyl)-2-hydroxyimino-acetate hydrochloride; 2-(Z)-(Hydroxyimino)-2-<2-<(triphenylmethyl)amino>thiazol-4-yl>acetate hydrochloride; ethyl 2-(tritylamino)-a-(hydroxyimino)thiazoleacetate HCl; ethyl 2-(2-tritylaminothiazole-4-yl)-2-hydroxyimino acetate hydrochloride

物化性质

• 沸点: 649.7ºC at 760 mmHg
• 熔点: 176-180ºC (dec.)(lit.)
• 分子式: C₂₆H₂₄ClN₃O₃S
• 分子量: 494.00500
• 闪点: 346.8ºC
• 精确质量: 493.12300
• PSA: 112.05000
• LogP: 6.16350

MSDS

Name: Ethyl 2-(2-tritylaminothiazole-4-yl)-2-hydroxyiminoacetate Material Safety Data Sheet Synonym: Ethyl (Z)-alpha-(hydroxyimino)-2-(tritylamino)thiazol-4-acetate hydrochlorid CAS: 66339-00-2 Section 1 - Chemical Product MSDS Name:Ethyl 2-(2-tritylaminothiazole-4-yl)-2-hydroxyiminoacetate Material Safety Data Sheet Synonym:Ethyl (Z)-alpha-(hydroxyimino)-2-(tritylamino)thiazol-4-acetate hydrochlorid Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 66339-00-2 Ethyl 2-(2-tritylaminothiazole-4-yl)-2 97 266-321-5 Hazard Symbols: XN Risk Phrases: 20/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation and if swallowed.Moisture sensitive.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Keep from contact with moist air and steam. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 66339-00-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder and chunks Color: off-white Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 174 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: C26H23N3O3S.HCl Molecular Weight: 493.95 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. May decompose on exposure to moist air or water. Conditions to Avoid: Incompatible materials, moisture, excess heat, strong oxidants. Incompatibilities with Other Materials: Moisture, water. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 66339-00-2 unlisted. LD50/LC50: Not available. Carcinogenicity: Ethyl 2-(2-tritylaminothiazole-4-yl)-2-hydroxyiminoacetate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/22 Harmful by inhalation and if swallowed. Safety Phrases: WGK (Water Danger/Protection) CAS# 66339-00-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 66339-00-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 66339-00-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi

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文献：Roussel Uclaf Patent: US4196205 A1, 1980 ;

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