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主要用于合成颜料红57#时的添加剂和蓝色相调节剂。
| 中文名 | 4-氨基甲苯-2-磺酸 |
|---|---|
| 英文名 | 5-Amino-2-methylbenzenesulfonic acid |
| 中文别名 |
2-甲基-5-氨基苯磺酸
5-氨基-2-甲基苯磺酸 异4B酸 |
| 英文别名 |
Benzenesulfonic acid, 5-amino-2-methyl-
4-Amino-2-sulfotoluene 2-methyl-5-aminobenzene sulfonic acid p-Toluidine-m-sulfonic acid o-Toluenesulfonic acid,5-amino 3-amino-6-methylbenzene-1-sulfonic acid p-toluidine-3-sulfonic acid 4-Amino-o-toluenesulfonic acid 4-Methyl-3-sulfoaniline 4-Amino-toluol-2-sulfonsaeure 5-amino-2-methylbenzene sulfonic acid o-Toluenesulfonic acid, 4-amino- 3-Amino-6-methylbenzenesulfonic acid 4-amino-toluene-2-sulfonic acid MFCD00007911 2-Methyl-5-amino benzene sulfonic acid Benzenesulfonic acid,5-amino-2-methyl EINECS 204-282-8 5-Amino-2-methylbenzenesulfonic acid |
| 密度 | 1.4±0.1 g/cm3 |
|---|---|
| 熔点 | >295 °C (subl.)(lit.) |
| 分子式 | C7H9NO3S |
| 分子量 | 187.216 |
| 精确质量 | 187.030319 |
| PSA | 88.77000 |
| LogP | -0.60 |
| 外观性状 | 淡黄色结晶粉末 |
| 折射率 | 1.610 |
| 储存条件 | 密封于阴凉、干燥处保存。确保工作间有 良好的通风设施。储存的地方远离氧化剂、火源、水源。 |
| 稳定性 | 避免与氧化物、水分接触。 |
| 水溶解性 | 56 g/L (20 ºC) |
| 分子结构 | 五、分子性质数据： 1、 摩尔折射率：45.34 2、 摩尔体积（m3/mol）：130.7 3、 等张比容（90.2K）：366.4 4、 表面张力（dyne/cm）：61.7 5、 极化率（10-24cm3）：17.97 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:0.4 2.氢键供体数量:2 3.氢键受体数量:4 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积88.8 7.重原子数量:12 8.表面电荷:0 9.复杂度:244 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：浅棕色晶体状粉末。 2. 密度（g/mL,25℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg,25ºC）：未确定 12. 饱和蒸气压（kPa, ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive. Potential Health Effects Eye: Causes eye irritation. Causes severe eye burns. Causes eye burns. Skin: Causes skin burns. Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Inhalation: May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Use only in a chemical fume hood. Discard contaminated shoes. Storage: Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Corrosives area. Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 118-88-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: weak odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: > 200 deg C Autoignition Temperature: > 500 deg C (> 932.00 deg F) Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: soluble in water Specific Gravity/Density: Molecular Formula: Molecular Weight: 187.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Not available. Hazardous Decomposition Products: Nitrogen oxides, sulfur dioxide, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 118-88-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Aminotoluene-2-sulfonic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: ARYLSULPHONIC ACIDS, SOLID Hazard Class: 8 UN Number: 2583 Packing Group: II IMO Shipping Name: ARYLSULPHONIC ACIDS, SOLID Hazard Class: 8 UN Number: 2583 Packing Group: II RID/ADR Shipping Name: ARYLSULPHONIC ACIDS, SOLID Hazard Class: 8 UN Number: 2583 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 25 Avoid contact with eyes. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 118-88-7: 2 Canada CAS# 118-88-7 is listed on Canada's NDSL List. CAS# 118-88-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 118-88-7 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水有轻微的危害。
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| 风险声明 (欧洲) | R20/21/22 |
|---|---|
| 安全声明 (欧洲) | S26-S36/37/39 |
| 危险品运输编码 | 2585 |
| 包装等级 | III |
| 危险类别 | 8 |
| 海关编码 | 2921430090 |
| 上游产品 10 | |
|---|---|
| 下游产品 6 | |
| 海关编码 | 2921430090 |
|---|---|
| 中文概述 | 2921430090 甲苯胺及其衍生物以及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 原产地证据文件及编号(例 附原产地证书, 原产于欧盟的 |
| Summary | HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
