前往化源商城
入驻化源商城

品牌现货直购
供应商:我要出现这里






查看所有供应商和价格请点击:

39148-24-8生产厂家

39148-24-8价格

39148-24-8

39148-24-8结构式
39148-24-8结构式
  • 常用中文名:三乙膦酸铝
  • 常用英文名:Fosetyl-aluminum
  • CAS号:39148-24-8
  • 分子式:C2H7O3P.1/3Al
  • 分子量:354.104
  • 相关类别: 化学农药原药 杀菌剂 有机磷杀菌剂
  • 发布时间:2018-08-06 16:03:21
  • 更新时间:2024-01-02 11:20:38
  • Fosetyl-aluminum (Fosetyl-Al) 是许多杀菌剂中抗霜霉病的活性成分。Fosetyl-aluminum 被用于控制农业和园艺作物上由疫霉引起的许多疾病。

化源商城直购

中文名 三乙膦酸铝
英文名 fosetyl-Al
中文别名 疫霉灵
三-(乙基膦酸)铝
乙膦铝
藻菌磷
疫霜灵
英文别名 Fosetyl aluminium
fosetyl-aluminium
Aluminium tris(ethyl phosphonate)
Aluminum tris(ethyl phosphonate)
Aluminum tris(O-ethylphosphonate)
aluminum tris[ethyl phosphonate]
fosetyl-aluminum
Phosphonic acid, ethyl ester, aluminum salt (3:1)
EINECS 254-320-2
熔点 >300ºC
分子式 C2H7O3P.1/3Al
分子量 354.104
精确质量 353.997894
PSA 218.49000
LogP 2.86680
外观性状 solid
储存条件

在0-6°C下保存

稳定性

常规情况下不会分解,没有危险反应

20℃时在水中的溶解度为120g/L,在乙腈或丙二醇中溶解度均小于80g/L。挥发性小,蒸气压在20℃时极小。原药及加工品在通常贮存条件下均稳定。遇碱分解。

在试验条件下未发现致畸、致癌、致突变现象。对皮肤无刺激作用。

计算化学

1、 疏水参数计算参考值(XlogP):未确定

2、 氢键供体数量:0

3、 氢键受体数量:9

4、 可旋转化学键数量:3

5、 拓扑分子极性表面积(TPSA):148

6、 重原子数量:19

7、 表面电荷:3

8、 复杂度:47.2

9、 同位素原子数量:0

10、 确定原子立构中心数量:0

11、 不确定原子立构中心数量:0

12、 确定化学键立构中心数量:0

13、 不确定化学键立构中心数量:0

14、 共价键单元数量:4

更多

1. 性状:纯品为白色无臭味结晶,工业品为白色粉末。

2. 密度(g/mL,20 ºC):未确定

3. 相对蒸汽密度(g/mL,空气=1): 未确定

4. 熔点(ºC):>300

5. 沸点(ºC):未确定

6. 沸点(ºC, 22mm hg):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:未确定

毒理学数据:

1、急性毒性:大鼠经口LD50:5 gm/kg;

大鼠腹腔LD50:550 mg/kg;

大鼠经皮LD50:>3200 mg/kg;

小鼠经口LD50:3700 mg/kg;

小鼠经皮LD50:>3200 mg/kg;

小狗经口LDLo:>2140 mg/kg;

兔子经皮LD50:> 2 gm/kg;

兔子经口LD50:2680 mg/kg。

豚鼠经口LD50:2780 mg/kg

鹌鹑经口LD50:4997 mg/kg

生态学数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SZ9640000
CAS REGISTRY NUMBER :
39148-24-8
LAST UPDATED :
199712
DATA ITEMS CITED :
24
MOLECULAR FORMULA :
C6-H18-O9-P3.Al
MOLECULAR WEIGHT :
354.13
WISWESSER LINE NOTATION :
2OPHO&O-AL-OPHO&O2&OPHO&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555410 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C147,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,443,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
550 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,565,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,443,1991
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,565,1977
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
>2140 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 33,224,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2680 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,565,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C147,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2780 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,565,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
4997 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,565,1977 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993

危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R41
安全声明 (欧洲) S26
危险品运输编码 UN2783 (solid); UN3018(liquid
RTECS号 SZ9640000

1.三氯化磷与乙醇在少量水存在下脱去氯化氢,生成二乙基亚磷酸酯和少量一乙基亚磷酯;在稍过量氨水或氢氧化钠作用下,生成一乙基亚磷酸铵(或钠);再与稍过量的硫酸铝反应生成三乙膦酸铝。

2.可由乙醇与三氯化磷反应生成二乙基亚磷酸,再制成铵盐,加硫酸铝复分解制得产品。

39148-24-8 preparation