14096-82-3

• 常用中文名：三羰基亚硝酰基钴
• 常用英文名：cobalt tricarbonyl nitrosyl
• CAS号：14096-82-3
• 分子式：C₃CoNO₄
• 分子量：172.97000
• 发布时间：2018-02-15 08:00:00
• 更新时间：2024-04-02 11:59:15

名称

• 中文名: 三羰基亚硝酰基钴
• 英文名: cobalt tricarbonyl nitrosyl
• 英文别名: Cobalt,tricarbonylnitrosyl-,(T-4); TRICARBONYLNITROSYLCOBALT; Co(CO)3NO; EINECS 237-945-5; MFCD00016014

物化性质

• 沸点: 50ºC
• 熔点: -11ºC
• 分子式: C₃CoNO₄
• 分子量: 172.97000
• 精确质量: 172.91600
• PSA: 29.43000
• 储存条件:

  常温密闭避光，通风干燥惰性气体下

• 稳定性:

  常温常压下稳定

  避免的物料：氧化物 卤素 空气 热

• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：172.915932 Da

  8、标称质量：173 Da

  9、平均质量：172.9696 Da

• 更多:

  1. 性状：深红色液体

  2. 密度（g/mL,25/4℃）：2.09

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：-1.05

  5. 沸点（ºC,常压）：48.6

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：不适用的

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不能拌和的或难以拌和的

MSDS

Section 1: Product Identification Chemical Name:Cobalt tricarbonyl nitrosyl CAS Registry Number:14096-82-3 Formula:Co(CO)3NO EINECS Number:237-945-5 Chemical Family:metal carbonyl complexes Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14096-82-3100%0.02mg/m3no data Section 3: Hazards Identification Harmful by inhalation, in contact with skin and if swallowed. Inhalation can lead to headaches and dizziness. Emergency Overview: Prolonged exposure can lead to convulsions and coma. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause mild irritation to the eyes. Skin Contact:Harmful in contact with skin. May cause mild irritation to the skin. Inhalation:Harmful through inhalation. Inhalation could lead to dizziness and headache. Ingestion:Harmful if swallowed. Harmful by inhalation, in contact with skin and if swallowed. Inhalation can lead to headaches and dizziness. Acute Health Affects: Prolonged exposure can lead to convulsions and coma. Chronic Health Affects:No information on long term exposure. NTP:No IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as Inhalation: possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital. Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious). Ingestion: Induce vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry chemical or foam If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus. Hazardous Combustion andcarbon monoxide, carbon dioxide, and cobalt oxides. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable liquid. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small quantities can be mixed with sodium carbonate or vermiculite and swept up. If large quantities are Spill and Leak Procedures: spilled, and ventilation is not available, personnel should be fitted with a self- contained breathing apparatus. SECTION 7: Handling and Storage Handling and Storage: SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling chemical substances. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:This product should be handled in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance 29 CFR 1910.134. Ventilation:This product should be handled in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:dark red liq. Molecular Weight:172.97 Melting Point:no data Boiling Point:50°C Vapor Pressure:no data Specific Gravity:1.47 Odor:musty odor Solubility in Water:Insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged contact with air. Incompatibility:Oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, cobalt oxides. SECTION 11: Toxicological Information RTECS Data:No specific information available on this product. Carcinogenic Effects:Possible carcinogen (as Co) Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available. SECTION 13: Disposal Considerations Disposal:Dispose of this material according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable liquids, toxic, N.O.S. Hazard Class (CFR):3 Additional Hazard Class (CFR):6.1 Packaging Group (CFR):II UN ID Number (CFR):UN# 1992 Shipping Name (IATA):Flammable liquid, toxic, N.O.S. Hazard Class (IATA):3 Additional Hazard Class (IATA):6.1 Packaging Group (IATA):II UN ID Number (IATA):UN# 1992 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See Category Code N096 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响；没有已知的敏化影响。 生态学数据: 对水体是危害的，即使小量产品不能接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 风险声明 (欧洲): 20/21/22-40
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 3281
• 包装等级: II
• 危险类别: 6.1