116-71-2

• 常用中文名：还原蓝20
• 常用英文名：Violanthrone
• CAS号：116-71-2
• 分子式：C₃₄H₁₆O₂
• 分子量：456.490
• 相关类别： 染料及颜料 染料 还原染料
• 发布时间：2018-06-23 18:19:41
• 更新时间：2026-07-01 11:33:52
• 【用途一】
  主要用于棉织物的染色和印花
  【用途二】
  还原深蓝 BO 主要用于棉纤维的染色，亲和力好，上色快，匀染性中等。较少用于印花，较多用于拼色。可用于蚕丝、黏胶纤维、黏棉、维棉的染色，也用于涤棉混纺织物与分散染料同浴热熔染色，还用于制备有机颜料。

名称

• 中文名: 还原深蓝BO
• 英文名: Violanthrone
• 中文别名: 还原海军蓝RA; 还原深蓝BO(还原蓝20); 还原深蓝BO/还原蓝 18; 还原深紫4BL; 还原蓝 18; 士林深蓝BO; 还原深蓝20; 颜料蓝65; 蒽[9,1,2-CDE]苯并[RST]戊芬-5,10-二酮; 聯苯并蒽酮; 还原深蓝BOA; 紫蒽酮; C.I.还原蓝20
• 英文别名: fenanthrendkbluebo; Ahcovat Dark Blue BO; Anthra[9,1,2-cde]benzo[rst]pentaphen-5,10-dione; tinondkbluemba; sandothrenedkbluenmba; Violanthrone A; DIBENZANTHRONE; Violanthrone (8CI); Youhaothrene Dk Blue BO; MFCD00046330; Vat Blue BO; EINECS 204-152-0; solanthrenedkbluef-ba; Tinon Dk Blue MBA; AnthramDk Blue BO; Indanthrene Dk Blue BO; Tinon Dark Blue BOA; Indanthren Dk Blue BOA; Solanthrene Dk Blue F-BA; Hydroform DeBlue BOA; Irgalite Blue 2R; Intravat Dk Blue BO; Tyrian Dk Blue I-BOA; Paradone Dark Blue; Patcovat Dk Blue BOA; Bianthrone A; hydroformdeblueboa; Dibenzanthrone; ahcovatdkbluebo; Dycosthren Dk Blue; Tinon Dk Blue BOR; Tinon Dark Blue BO; sandothrenedkbluenbm; Tinon Dk Blue BO; sandothrenedkblueboa; Dark Blue 2R; sandothrenedkbluenbo; Hebeithrene Dk Blue BO; tinondkbluemb; solanthrenedkblueboa; Amanthrene Supra Dk Blue BO; tinondkbluebor; IndanthrenDkBlueBO; VAT BLUE 20; VIOLANTHRONE; indanthrendkblueboa; solanthrenedkblueb; Tinon Dk Blue BOA; Sandothrene Liquid Dk Blue NBO; solanthrenedkblueba; leucosoldkbluebr; tinondkblueboa; irgaliteblue2r; Amanthrene Dk Blue BO; Vat Blue-20; 5,10-Violanthrenedione; Ahcovat Dk Blue BO; Solanthrene Dk Blue BA; sandothrenedkbluenboa; Vat Dk Blue BO UL Conc; Trianthrene Dk Blue BOA; Anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-dione; C.I; Tinon Dk Blue MB; Solanthrene Dk Blue B; Vat Blue 18; Leucosol Dk Blue BR; tinondkbluebo; indanthrenedkbluebo; Blue BO; Cibanone Blue BOA-01; amanthrenedkbluebo

物化性质

• 密度: 1.5±0.1 g/cm3
• 分子式: C₃₄H₁₆O₂
• 分子量: 456.490
• 精确质量: 456.115021
• PSA: 34.14000
• LogP: 9.13
• 外观性状: 蓝黑色至黑色粉末
• 折射率: 1.926
• 储存条件: 室温，干燥密封
• 稳定性:

  于浓硫酸中呈紫黑色，稀释后产生紫黑色沉淀。于保险粉碱性溶液中呈暗紫色，于酸性液中呈暗红色。

• 分子结构:

  1、 摩尔折射率：145.65

  2、 摩尔体积（cm³/mol）：306.8

  3、 等张比容（90.2K）：925.0

  4、 表面张力（dyne/cm）：82.5

  5、 极化率（10-24cm3）：57.74

• 计算化学:

  1.疏水参数计算参考值（XlogP）:8

  2.氢键供体数量:0

  3.氢键受体数量:2

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积34.1

  7.重原子数量:36

  8.表面电荷:0

  9.复杂度:877

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1.性状：蓝黑色粉末。

  2.溶解性：不溶于水、乙醇，微溶于丙酮、氯仿、邻氯苯酚、吡啶、甲苯，溶于四氢萘、二甲苯 (呈红色带红色荧光溶液)。

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : JE2310000 CAS REGISTRY NUMBER : 116-71-2 LAST UPDATED : 199710 DATA ITEMS CITED : 8 MOLECULAR FORMULA : C34-H16-O2 MOLECULAR WEIGHT : 456.50 WISWESSER LINE NOTATION : L6 G666 R6 B6 V6 E&6 U6 4ABVW K& MV K&VJ HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(4),93,1990 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : RPTOAN Russian Pharmacology and Toxicology (English Translation). Translation of FATOAO. (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey, UK) V.30- 1967- Volume(issue)/page/year: 40,137,1977 TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(4),93,1990 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2600 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : RPTOAN Russian Pharmacology and Toxicology (English Translation). Translation of FATOAO. (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey, UK) V.30- 1967- Volume(issue)/page/year: 40,137,1977 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 60 gm/kg/30D-I TOXIC EFFECTS : Liver - liver function tests impaired Kidney, Ureter, Bladder - other changes REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(4),93,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9930 No. of Facilities: 193 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 2890 (estimated) No. of Female Employees: 578 (estimated)

安全

• 风险声明 (欧洲): R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
• 安全声明 (欧洲): S22-S36/37/39
• 危险品运输编码: 2811
• 包装等级: III
• 危险类别: 6.1
• 海关编码: 2914399090

合成路线

上下游产品

上游产品  9
116-96-1 81-96-9 82-05-3 116-90-5
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82-04-2
下游产品  4
128-59-6 128-58-5 76415-41-3 81-31-2

制备

以苯绕蒽酮 (benzanthrone) 为原料，在精萘介质中用氢氧化钾和乙酸钠碱熔缩合，经回收精萘后，进行精制处理得成品。

海关

海关编码	2914399090
中文概述	2914399090. 其他不含其他含氧基的芳香酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙酮报明包装
Summary	2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%