128-58-5

• 常用中文名：还原绿1
• 常用英文名：Vat Green 1
• CAS号：128-58-5
• 分子式：C₃₆H₂₀O₄
• 分子量：516.54200
• 相关类别： 染料及颜料 染料 还原染料
• 发布时间：2018-08-27 20:18:54
• 更新时间：2026-07-14 19:08:07

• 主要用于棉织物的染色和印花，也可用于涤/ 棉的染色和塑料的着色。

  还原艳绿 FFB 用于棉纤维染色和棉布印花，匀染性很好，亲和力较高。可单独使用得鲜艳绿色，但更多用于拼色，可得系列绿色谱，如果绿、浅绿、深绿、蓝绿等。也用于染蚕丝、羊毛、黏胶纤维以及黏棉、维棉混纺织物。还可用于塑料、肥皂、纸张着色。

名称

• 中文名: 还原绿1
• 英文名: Vat Green 1
• 中文别名: 还原艳绿3B; 还原艳绿FFB(还原绿1); 士林绿FFB; 还原艳黑 3B; 还原艳绿FFB; VAT EEN 1,CERTIFIED 标准品; 士林艳绿F2F; C.I.还原绿1; 还原绿 1
• 英文别名: 16,17-dimethoxyviolanthrene-5,10-dione; cibanonebrillianteenfbf; caledonjadeeenxbn; MFCD00046331; 16,17-dimethoxyviolanthrone; ahcovatjadeeenbda; 16,17-dinaphtho(1,2,3-cd:3',2',1'-lm)perylene-5,10-dione; brillianteenanthraquinones; ci59825; mikethrenebrillianteenb; 16,17-Dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphen-5,10-dion; indanthrenebrillianteenb; benzadonejadeeenxbn; ahcovatprintingjadeeenb; indanthrenebrillianteenffb; mikethrenebrillianteenffb; ahcovatprintingjadeeenbda; calcoloidjadeeenn; benzadonejadeeenxn; c.i; calcoloidjadeeennc; indanthrenbrillianteenffbextrapure; civatgreen1; civateen1; 1,2-cde]benzo[rst]pentaphene-5,10-dione,16,17-dimethoxy-anthra[; indanthrenebrillianteenbn; belanthrenejadeeen; zelenkypova1; IndanthrenBrillianteenB,FB,FFB,FFBD; mayvatjadeeen; indanthrenbrillianteenb; fenanthrenbrillianteenb; amanthrenebrillianteenjp; Jade Green XBN; Green FFB; amanthrenebrillianteenj; helanthreneeenb; Navinon Jade Green FFBU/C; ahcovatjadeeenb; C.I.VatGreen; Vatjadegreen; calcoloidjadeeennp; amanthrenesupraeenjf; C.I.Vateen; 16 17-DIMETHOXYDIBENZANTHRONE; brillianteens; caledonjadeeenxn; cbanthrenebrillianteen; C.I.VATGREENI; dimethoxyviolanthrone; 16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-dione; 16,17-dimethoxy-violanthron; JADE EEN BASE; 16,17-DIMETHOXYVIOLANTHRONE; mikethreneeenffb; aticvatjadeeenxbn; CaledoneenXBN,XBNQF; amanthreneeenjf; C.I.Vateen1; benzadonejadeeenb; indanthrenbrillianteenffb; cibanonebrillianteen2bf; caledonprintingjadeeenxbn; caledonjadeeen; caledonprintingjadeeenxn; indanthrenbrillianteenfb; benzadonejadeeenx; CibanoneBrillianteenBF,2BF,BFD; cbanthrenebrillianteeng; EINECS 204-896-6; aticvatprintingjadeeenxbn; 2,3-cd:3’,2’,1’-lm)perylene-5,10-dione,16,17-dimethoxy-dinaphtho(

物化性质

• 密度: 1.455 g/cm3
• 分子式: C₃₆H₂₀O₄
• 分子量: 516.54200
• 精确质量: 516.13600
• PSA: 52.60000
• LogP: 8.17720
• 外观性状: 固体
• 折射率: 1.799
• 稳定性: Stable. Incompatible with strong oxidizing agents.
• 分子结构:

  1、 摩尔折射率：159.01

  2、 摩尔体积（cm³/mol）：354.8

  3、 等张比容（90.2K）：1042.2

  4、 表面张力（dyne/cm）：74.3

  5、 极化率（10-24cm3）：63.03

• 计算化学:

  1.疏水参数计算参考值（XlogP）:8

  2.氢键供体数量:0

  3.氢键受体数量:4

  4.可旋转化学键数量:2

  5.互变异构体数量:无

  6.拓扑分子极性表面积52.6

  7.重原子数量:40

  8.表面电荷:0

  9.复杂度:971

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1.性状：深绿色粉末。

  2.溶解性：不溶于水、乙醇、氯仿、甲苯、微溶于丙酮、邻氯苯酚、硝基苯、吡啶 (热)，溶于四氢萘 (温热)。于浓硫酸中呈红光紫色，稀释后产生绿色沉淀。于保险粉碱性溶液中呈蓝色，于酸性液中呈艳红色。

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : JE2315500 CAS REGISTRY NUMBER : 128-58-5 BEILSTEIN REFERENCE NO. : 2068558 LAST UPDATED : 199710 DATA ITEMS CITED : 7 MOLECULAR FORMULA : C36-H20-O4 MOLECULAR WEIGHT : 516.56 WISWESSER LINE NOTATION : L6 G666 R6 B6 V6 E&6 U6 4ABVW K& MV K&VJ DO1 B&O1 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1330,1986 ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2600 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - other changes REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(10),88,1987 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 60 gm/kg/30D-I TOXIC EFFECTS : Liver - liver function tests impaired Liver - changes in liver weight Blood - changes in cell count (unspecified) REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(10),88,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2227 No. of Facilities: 15 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 29 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2227 No. of Facilities: 654 (estimated) No. of Industries: 9 No. of Occupations: 22 No. of Employees: 30730 (estimated) No. of Female Employees: 25444 (estimated)

安全

• 安全声明 (欧洲): S16-S26-S36/37/39
• 危险品运输编码: UN 3295 3/PG 1
• WGK德国: 3
• 海关编码: 2914509090

合成路线

6535-67-7 ~% 128-58-5

文献：DE413738 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 766

116-71-2 80-48-8 ~% 128-58-5

文献：GB636008 , ;

116-71-2 77-78-1 ~% 128-58-5

文献：GB636008 , ;

77-78-1 ~% 128-58-5

文献：US2140455 , ;

7664-93-9 3951-01-7 ~% 128-58-5

文献：US2148042 , ;

上下游产品

上游产品  5
6535-67-7 116-71-2 80-48-8 77-78-1
7664-93-9
下游产品  0

制备

以苯绕蒽酮为原料，在丁醇介质中加入氢氧化钾、乙酸钠、亚硝酸钠进行缩合，然后用二氧化锰在硫酸中氧化、闭环，经还原后进行甲基化得产物。最后经酸洗离析、水煮、干燥、粉碎得成品。

海关

海关编码	2914509090
中文概述	2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙酮报明包装
Summary	HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%