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| 中文名 | 邻苯基苯酚缩水甘油醚 |
|---|---|
| 英文名 | 2-[(2-phenylphenoxy)methyl]oxirane |
| 中文别名 |
3-(2-联苯)-1,2-环氧丙烷
2-联苯缩水甘油醚 |
| 英文别名 |
MFCD00046989
2-[(biphenyl-2-yloxy)methyl]oxirane 2-biphenylyl glycidyl ether {[(1,1'-biphenyl)-2-yloxy]methyl}-oxirane 3-(2-Xenyloxy)propylene oxide Biphenyl-2-yl 2,3-epoxypropyl ether 1,2-epoxy-3-(2-phenylphenoxy)propane OPP-G Ether,2-biphenylyl 2,3-epoxypropyl 3-(2-Biphenyloxy)propylene oxide Biphenyl-2-yloxymethyl-oxiran biphenyl-2-yloxymethyl-oxirane EINECS 230-451-0 |
| 密度 | 1.136g/cm3 |
|---|---|
| 沸点 | 120ºC (0.1 torr) |
| 熔点 | 30-32ºC |
| 分子式 | C15H14O2 |
| 分子量 | 226.27000 |
| 闪点 | 137.3ºC |
| 精确质量 | 226.09900 |
| PSA | 21.76000 |
| LogP | 3.13120 |
| 外观性状 | 白色至淡黄色低熔点固体 |
| 折射率 | 1.581 |
| 储存条件 | 密封于阴凉干燥处。 |
| 稳定性 | 遵照规格使用和储存则不会分解。 |
| 分子结构 | 1、 摩尔折射率：66.36 2、 摩尔体积（m3/mol：199.0 3、 等张比容（90.2K）：514.3 4、 表面张力（dyne/cm）：44.6 5、 极化率（10-24cm3）：26.30 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:3.2 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:4 5.互变异构体数量:无 6.拓扑分子极性表面积21.8 7.重原子数量:17 8.表面电荷:0 9.复杂度:235 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:1 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）： 无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：30-32 5. 沸点（ºC,常压）：120/0.1mmHg 6. 沸点（ºC,5.2kPa）： 无可用 7. 折射率： 无可用 8. 闪点（ºC）： 无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）： 无可用 19. 溶解性：无可用 |
Synonym:3-(2-Biphenylyloxy)-1,2-Epoxypropane; Ether, 2-Biphenyl 2,3-epoxypropyl Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 7144-65-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 120 deg C @ .10mmHg Freezing/Melting Point: 30.00 - 32.00 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C15H14O2 Molecular Weight: 226.27 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents, strong acids, strong bases. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 7144-65-2: RR0356000 LD50/LC50: Not available. Carcinogenicity: 2-Biphenylyl Glycidyl Ether - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 7144-65-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 7144-65-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 7144-65-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 试验方法： 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATAMUTATION DATA
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| 危害码 (欧洲) | Xi |
|---|---|
| 风险声明 (欧洲) | R36/37/38:Irritating to eyes, respiratory system and skin . |
| 安全声明 (欧洲) | S26-S37/39 |
| WGK德国 | 3 |
| RTECS号 | SL7800000 |
| 海关编码 | 2910900090 |
| 海关编码 | 2910900090 |
|---|---|
| 中文概述 | 2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
