16355-92-3

• 常用中文名：1,10-二碘癸烷
• 常用英文名：1,10-DIIODODECANE
• CAS号：16355-92-3
• 分子式：C₁₀H₂₀I₂
• 分子量：394.075
• 相关类别： 有机原料 烃类化合物及其衍生物 烃类卤化物
• 发布时间：2018-02-28 08:00:00
• 更新时间：2024-01-10 17:03:50
• 【用途一】
  主要用作医药中间体，也用于其它有机合成。

名称

• 中文名: 1,10-二碘癸烷
• 英文名: 1,10-Diiododecane
• 中文别名: 双碘癸烷
• 英文别名: EINECS 240-415-6; MFCD00001086; Decane, 1,10-diiodo-; 1,10-DIIODODECANE; Decamethylene Diiodide

物化性质

• 密度: 1.7±0.1 g/cm3
• 沸点: 349.7±0.0 °C at 760 mmHg
• 熔点: 33-35 °C(lit.)
• 分子式: C₁₀H₂₀I₂
• 分子量: 394.075
• 闪点: 146.7±14.5 °C
• 精确质量: 393.965424
• LogP: 6.49
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.556
• 储存条件: 常温密闭避光，通风干燥
• 稳定性:

  常温常压下稳定

  避免的物料： 氧化物 光
• 分子结构:

  1、 摩尔折射率：74.31

  2、 摩尔体积（m³/mol）：231.2

  3、 等张比容（90.2K）：577.9

  4、 表面张力（dyne/cm）：39.0

  5、 极化率（10^-24cm³）：29.46

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:9

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:12

  8.表面电荷:0

  9.复杂度:64.2

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1.性状：未确定

  2. 密度（g/mL,25/4 ℃ ）： 2,35 g/cm ³ 3. 相对蒸汽密度（g/mL,空气=1） ： 未确定

  4.熔点（ºC）：33-35°C(lit.); 5.沸点（ºC,常压）：197-200°C12mm Hg(lit.);

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：230°F; 9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Name: 1 10-Diiododecane 97% Material Safety Data Sheet Synonym: CAS: 16355-92-3 Section 1 - Chemical Product MSDS Name:1 10-Diiododecane 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 16355-92-3 1,10-Diiododecane 97 240-415-6 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Light sensitive.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. No information regarding eye irritation and other potential effects was found. Skin: May cause skin irritation. No information regarding skin irritation and other potential effects was found. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 16355-92-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystals Color: off-white crystal to orange liquid - after melting, Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 197.0 - 200.0 deg C @ 12.00mm Freezing/Melting Point: 28.00 - 32.00 deg C Autoignition Temperature: Not available. Flash Point: 110 deg C ( 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H20I2 Molecular Weight: 394.07 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen iodide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16355-92-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,10-Diiododecane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 16355-92-3: No information available. Canada CAS# 16355-92-3 is listed on Canada's NDSL List. CAS# 16355-92-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16355-92-3 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H315-H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S37/39
• 危险品运输编码: 2811
• WGK德国: 3
• 包装等级: III
• 危险类别: 6.1(b)
• 海关编码: 2903399090

合成路线

上下游产品

上游产品  9
112-47-0 2162-98-3 111-20-6 4101-68-2
61575-02-8 110-40-7 10471-28-0 53463-68-6
10034-85-2
下游产品  10
4543-66-2 30391-54-9 124-18-5 112-95-8
693-23-2 102119-87-9 1871-96-1 1191-67-9
32113-15-8 1420-40-2

制备

【方法一】
由癸二醇经氯化、置换而得。

海关

海关编码	2903399090
中文概述	2903399090. 其他无环烃的氟化、溴化或碘化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%