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| 中文名 | 5-氟-2-(三氟甲基)苯甲酰氯 |
|---|---|
| 英文名 | 5-fluoro-2-(trifluoromethyl)benzoyl chloride |
| 中文别名 | α,α,α,5-四氟邻甲基苯甲酰氯 |
| 英文别名 |
5-fluoro-2-trifluoromethylbenzoyl chloride
MFCD00083534 GVR CF FXFFF Benzoyl chloride, 5-fluoro-2-(trifluoromethyl)- α,α,α,5-Tetrafluoro-o-toluoyl chloride 5-Fluoro-2-(trifluoromethyl)benzoyl chloride 2-Trifluoromethyl-5-fluorobenzoyl chloride |
| 密度 | 1.5±0.1 g/cm3 |
|---|---|
| 沸点 | 213.3±40.0 °C at 760 mmHg |
| 熔点 | 169ºC(lit.) |
| 分子式 | C8H3ClF4O |
| 分子量 | 226.555 |
| 闪点 | 82.8±27.3 °C |
| 精确质量 | 225.980850 |
| PSA | 17.07000 |
| LogP | 3.55 |
| 蒸汽压 | 0.2±0.4 mmHg at 25°C |
| 折射率 | 1.453 |
| 储存条件 | 保存方法：密闭，阴凉，通风干燥处 |
| 稳定性 | 避氧化物、水分、碱 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:3.4 2.氢键供体数量:0 3.氢键受体数量:5 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积17.1 7.重原子数量:14 8.表面电荷:0 9.复杂度:228 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：黄色或无色的液体 2. 密度（g/mL20ºC）：1.5 3. 相对蒸汽密度（g/mL,空气=1）未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：168-169 6. 沸点（ºC3mmHg）：未确定 7. 折射率：n20/D1.463 8. 闪点（º F）：188 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：86 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：与水发生反应 |
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Revision number: 5
5-Fluoro-2-(trifluoromethyl)benzoyl Chloride SAFETY DATA SHEET Section1. IDENTIFICATION 5-Fluoro-2-(trifluoromethyl)benzoyl Chloride Product name: 5 Revision number: Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDS Category 4 Flammable liquids Category 1 Corrosive to metals HEALTH HAZARDS Category 1B Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Danger Signal word Combustible liquid Hazard statements May be corrosive to metals Causes severe skin burns and eye damage Precautionary statements: Keep away from flames and hot surfaces. [Prevention] Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Wear protective gloves and eye/face protection. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for [Response] breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/physician. Absorb spillage to prevent material damage. Store in a well-ventilated place. Keep cool. [Storage] Store locked up. Section2. HAZARDS IDENTIFICATION Dispose of contents/container through a waste management company authorized by [Disposal] the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Substance/mixture: 5-Fluoro-2-(trifluoromethyl)benzoyl Chloride Components: >98.0%(GC)(T) Percent: 216144-70-6 CAS Number: α,α,α,5-Tetrafluoro-o-toluoyl Chloride Synonyms: C8H3ClF4O Chemical Formula: Section4. FIRST AID MEASURES Remove victim to fresh air and keep at rest in a position comfortable for breathing. Inhalation: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Gently wash with plenty of Skin contact: soap and water. Immediately call a POISON CENTER or doctor/physician. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT Ingestion: induce vomiting. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Dry chemical, carbon dioxide. Suitable extinguishing media: Unsuitable extinguishing Water media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. from the chemical: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. When extinguishing fire, be sure to wear personal protective equipment. Special protective equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use extra personal protective equipment (self-contained breathing apparatus). Keep Personal precautions, protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non- emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Prevention of secondary Do not allow contact with water. Remove all sources of ignition. Fire-extinguishing devices should be prepared in case of a fire. Use spark-proof tools and explosion- hazards: proof equipment. Section7. HANDLING AND STORAGE Precautions for safe handling Section7. HANDLING AND STORAGE Handling is performed in a well ventilated place. Wear suitable protective equipment. Technical measures: Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling. Use a closed system, ventilation. Advice on safe handling: Avoid contact with skin, eyes and clothing. May develop pressure. Open carefully. Use corrosive resistant equipment. Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store in a cool, dark and well-ventilated place. Storage conditions: Store under inert gas. Protect from moisture. Store locked up. Store away from incompatible materials such as oxidizing agents. Moisture-sensitive Comply with laws. Keep only in original container. Packaging material: Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust. Also install safety shower and eye bath. Engineering controls: Personal protective equipment Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Impervious gloves. Hand protection: Safety goggles. A face-shield, if the situation requires. Eye protection: Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Physical state (20°C): Clear Form: Colorless - Slightly pale yellow Colour: No data available Odour: pH: No data available Melting point/freezing point:No data available 169°C Boiling point/range: 87°C Flash point: Flammability or explosive limits: No data available Lower: No data available Upper: 1.50 Relative density: Solubility(ies): No data available [Water] No data available [Other solvents] Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous Decomposes in contact with water and liberates toxic gases. reactions: Open flame, Moisture Conditions to avoid: Incompatible materials: Oxidizing agents, Bases, Water Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride, Hydrogen chloride products: Section11. TOXICOLOGICAL INFORMATION No data available Acute Toxicity: Section11. TOXICOLOGICAL INFORMATION Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: No data available Germ cell mutagenicity: Carcinogenicity: No data available IARC = No data available NTP = No data available Reproductive toxicity: Section12. ECOLOGICAL INFORMATION Ecotoxicity: No data available Fish: No data available Crustacea: No data available Algae: Persistence / degradability: No data available No data available Bioaccumulative potential(BCF): Mobility in soil No data available Log Pow: No data available Soil adsorption (Koc): No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION 8: Corrosive. Hazards Class: 3265 UN-No: Corrosive liquid, acidic, organic, n.o.s. Proper shipping name: II Packing group: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 1、其它有害作用：通常对水是稍微危害的，若无政府许可，勿将材料排入周围环境。
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| 符号 |
GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | C: Corrosive; |
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | S23-S26-S36/37/39-S45 |
| 危险品运输编码 | UN 3265 8/PG 2 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 8 |
| 海关编码 | 2916399090 |
| 海关编码 | 2916399090 |
|---|---|
| 中文概述 | 2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装 |
| Summary | 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |