3244-90-4

• 常用中文名：丙硫特普
• 常用英文名：aspon (tm)
• CAS号：3244-90-4
• 分子式：C₁₂H₂₈O₅P₂S₂
• 分子量：378.42500
• 相关类别： 化学农药原药 杀虫剂 有机氯杀虫剂
• 发布时间：2018-02-06 08:00:00
• 更新时间：2026-07-01 17:48:19

名称

• 中文名: 氯丹
• 英文名: dipropoxyphosphinothioyloxy-dipropoxy-sulfanylidene-λ5-phosphane
• 中文别名: 甲苯中丙硫特普标准品; 二硫代焦磷酸四丙酯; 甲苯中丙硫特普溶液标准物质; 乙腈中丙硫特普; 标准物质/甲苯中丙硫特普; 丙硫特普/氯丹; 甲苯中丙硫特普; 丙硫特普杀虫剂标准品
• 英文别名: propylthiopyrophosphate; propylthiopyrophosphate[((pro)2p(s))2o]; thiodiphosphoricacid[((ho)2p(s))2o],tetrapropylester; TETRA-N-PROPYL DITHIONOPYRO-PHOSPHATE; ASPON STANDD; ASPON; l^{5}-phosphane; ASPON, 50MG, NEAT; Tetra-n-propyl dithionopyrophosphate; ent16; Tetra-O-propyl-1,2-dithio-phosphat; O,O,O',O'-TETRAPROPYL DITHIOPYRO-PHOSPHATE; Tetra-n-propyl dithiopyrophosphate; ASPON (TM); tetrapropyldithiopyrophosphate; a42; Propyl thiopyrophosphate; O,O,O',O'-tetrapropyl pyrophosphorothioate; A 42; EINECS 221-817-0; tetrapropyldithiodifosfat; tetrapropylthiodiphosphate; 1,2-Dithio-diphosphorsaeure-tetra-O-propylester; dipropoxythiophosphoryloxy-dipropoxy-thioxo-phosphorane; O,O,O,O-TETRAPROPYLDITHIO-PYROPHOSPHATE; NSC2550; Caswell No. 845A; thiopyrophosphoricacid,tetrapropylester; 1,2-dithio-diphosphoric acid tetra-O-propyl ester; ENT 16,894; dipropoxyphosphinothioyloxy-dipropoxy-sulfanylidene; Stauffer asp-51; ASP 51; thiopyrophosphoricacid[((ho)2ps)2o],tetrapropylester; staufferasp-51; ASP-51; NSC-2550; O-propyl-P-(propoxy)catenabis(propoxythio-lambda5-phosphoxane); Aspon 100 μg/mL in Acetonitrile; bis-o,o-di-n-propylphosphorothionicanhydride; e8573; Aspon (TM) 50mg [3-4]; tetra-n-propyldithiopyrophosphate; o,o,o,o,-tetra-n-propyldithiopyrophosphate; Thiodiphosphoric acid ([(HO)2P(S)]2O), OP,OP,OP',OP'-tetrapropyl ester; Aspon in Acetonitrile; Tetrapropyl thiodiphosphate; 0,0,0,0-tetrapropyldithiopyrophosphate; C10305000 Aspon

物化性质

• 密度: 1.173g/cm3
• 沸点: 381.6ºC at 760mmHg
• 熔点: -44.9°C
• 分子式: C₁₂H₂₈O₅P₂S₂
• 分子量: 378.42500
• 闪点: 184.6ºC
• 精确质量: 378.08500
• PSA: 129.95000
• LogP: 6.45960
• 外观性状: liquid
• 折射率: 1.498
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、 摩尔折射率：94.63

  2、 摩尔体积（m³/mol）：322.4

  3、 等张比容（90.2K）：835.0

  4、 表面张力（dyne/cm）：44.9

  5、 极化率（10^-24cm³）：37.51

• 计算化学:

  1.疏水参数计算参考值（XlogP）:6

  2.氢键供体数量:0

  3.氢键受体数量:7

  4.可旋转化学键数量:14

  5.互变异构体数量:无

  6.拓扑分子极性表面积110

  7.重原子数量:21

  8.表面电荷:0

  9.复杂度:299

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：149

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

毒性和生态

毒理学数据: 1。 试验方法：肌肉注射 摄入剂量： 4410微克/千克 测试对象：啮齿动物-鼠 毒性类型：急性 毒性作用：详细的毒副作用没有报告以外的其他致死剂量值 2 。 试验方法：行政上的皮肤 摄入剂量： 3830毫克/千克 测试对象：啮齿动物-兔 毒性类型：急性 毒性作用： 详细的毒副作用没有报告以外的其他致死剂量值 3 。 试验方法：口服 摄入剂量： 436毫克/千克 测试对象：鸟类-鸡 毒性类型：急性 毒性作用： 1.嗜睡（普通抑郁活动） 2.惊厥或癫痫阈 3.共济失调 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。 CHEMICAL IDENTIFICATION RTECS NUMBER : XN4550000 CHEMICAL NAME : Thiopyrophosphoric acid, tetrapropyl ester CAS REGISTRY NUMBER : 3244-90-4 BEILSTEIN REFERENCE NO. : 1715467 LAST UPDATED : 199612 DATA ITEMS CITED : 15 MOLECULAR FORMULA : C12-H28-O5-P2-S2 MOLECULAR WEIGHT : 378.46 WISWESSER LINE NOTATION : 3OPS&O3&OPS&O3&O3 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 450 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1800 mg/kg TOXIC EFFECTS : Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Behavioral - excitement REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 2,88,1960 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1100 mg/kg TOXIC EFFECTS : Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Behavioral - convulsions or effect on seizure threshold Behavioral - excitement REFERENCE : AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 8,350,1953 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,379,1971 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 8 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CJCHAG Canadian Journal of Chemistry. (National Research Council of Canada, Publication Sales and Distribution, Ottawa ON K1A OR6, Canada) V.29- 1951- Volume(issue)/page/year: 34,1819,1956 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 3250 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CJCHAG Canadian Journal of Chemistry. (National Research Council of Canada, Publication Sales and Distribution, Ottawa ON K1A OR6, Canada) V.29- 1951- Volume(issue)/page/year: 34,1819,1956 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intramuscular SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 4410 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CJCHAG Canadian Journal of Chemistry. (National Research Council of Canada, Publication Sales and Distribution, Ottawa ON K1A OR6, Canada) V.29- 1951- Volume(issue)/page/year: 34,1819,1956 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 3830 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 1,42,1968 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - chicken DOSE/DURATION : 436 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 6,147,1964 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

安全

• 危害码 (欧洲): Xn,N
• 风险声明 (欧洲): 21/22-50/53
• 安全声明 (欧洲): S60;S61;S36/S37
• 危险品运输编码: UN 3018
• RTECS号: XN4550000
• 包装等级: III
• 危险类别: 6.1(b)

合成路线

2524-05-2 ~% 3244-90-4

文献：Journal of the American Chemical Society, , vol. 73, p. 4670,4673

2524-05-2 58861-80-6 ~0% 3244-90-4 135492-41-0

文献：Sapozhnikova, Zh. Z.; Prokof'eva, A. F.; Volkova, V. N.; Negrebetskii, V. V.; Prokovskaya, L. A.; Mel'nikov, N. N. J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 2 p. 406 - 415,368 - 376

99822-19-2 2524-05-2 ~0% 3244-90-4 135492-44-3

文献：Sapozhnikova, Zh. Z.; Prokof'eva, A. F.; Volkova, V. N.; Negrebetskii, V. V.; Prokovskaya, L. A.; Mel'nikov, N. N. J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 2 p. 406 - 415,368 - 376

2524-05-2 58861-80-6 ~0% 3244-90-4 134202-28-1

文献：Sapozhnikova, Zh. Z.; Prokof'eva, A. F.; Volkova, V. N.; Negrebetskii, V. V.; Prokovskaya, L. A.; Mel'nikov, N. N. J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 2 p. 406 - 415,368 - 376

88351-47-7 ~% 3244-90-4

文献：DE896644 , ;

88351-47-7 71-43-2 ~% 3244-90-4

文献：DE896644 , ;

上下游产品

上游产品  5
2524-05-2 58861-80-6 99822-19-2 88351-47-7
71-43-2
下游产品  0