84-11-7

• 常用中文名：菲醌
• 常用英文名：Phenanthrene-9,10-dione
• CAS号：84-11-7
• 分子式：C₁₄H₈O₂
• 分子量：208.212
• 相关类别： 化学试剂 有机试剂 多环化合物
• 发布时间：2018-03-04 08:00:00
• 更新时间：2024-01-02 14:46:35
• 【用途一】
  菲醌本身是农药，可以用作杀菌剂、拌种剂、电子照相，可用作光导材料、光敏阻焊剂和纸张防腐剂。
  【用途二】
  菲醌用于有机合成，可用来生产苯绕蒽酮。菲醌具有抑菌能力，用于拌种可防止谷物黑穗病、棉花苗期病，还可作为纸浆防腐剂。经氢氧化钠处理后可制得多效能的植物生长调节剂整形素。

名称

• 中文名: 菲醌
• 英文名: 9,10-phenanthroquinone
• 中文别名: 9,10-菲蒽; 9,10-菲二酮; 菲醌 PHENANTHRENEQUINONE
• 英文别名: Phenanthrenequinone; MFCD00001163; 9,10-phenanthraquinone; 9,10-Phenanthrenedione; phenanthrene-9,10-dione; EINECS 201-515-5; 9,10-Phenanthrenequinone

物化性质

• 密度: 1.3±0.1 g/cm3
• 沸点: 360.0±0.0 °C at 760 mmHg
• 熔点: 209-212 °C(lit.)
• 分子式: C₁₄H₈O₂
• 分子量: 208.212
• 闪点: 163.1±4.4 °C
• 精确质量: 208.052429
• PSA: 34.14000
• LogP: 3.13
• 外观性状: 黄色晶体粉末
• 蒸汽压: 0.0±0.8 mmHg at 25°C
• 折射率: 1.659
• 储存条件:

  本品应密封于阴凉干燥处保存。

  采用内衬塑料袋，外套编织袋包装，贮存于阴凉、干燥、通风处，防晒、防潮，远离火种、热源。按一般化学品规定贮运。

• 稳定性:

  本品可通过皮肤吸收中毒。动物试验结果，小鼠经口最低中毒量２０ｍｇ／ｋｇ（连续一日）。操作人员应穿戴防护用具。

• 分子结构:

  1、 摩尔折射率：58.66

  2、 摩尔体积（cm³/mol）：159.0

  3、 等张比容（90.2K）：434.8

  4、 表面张力（dyne/cm）：55.8

  5、 极化率（10^-24cm³）：23.25

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：2.5

  2、 氢键供体数量0

  3、 氢键受体数量：2

  4、 可旋转化学键数量：0

  5、 拓扑分子极性表面积（TPSA）：34.1

  6、 重原子数量：16

  7、 表面电荷：0

  8、 复杂度：289

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：0

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：1

• 更多:

  1. 性状：橙黄色针状结晶。

  2. 密度（g/mL,25/4℃）：1.405

  3. 相对密度（20℃，4℃）：1.405²²

  4. 熔点（ºC）：209℃

  5. 沸点（ºC,常压）：360℃以上

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不溶于水，微溶于乙醇、苯、醋酸乙酯，溶于乙醚和热醋酸

MSDS

Name: Phenanthrenequinone 98% (uv-vis) Material Safety Data Sheet Synonym: CAS: 84-11-7 Section 1 - Chemical Product MSDS Name:Phenanthrenequinone 98% (uv-vis) Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 84-11-7 Phenanthrenequinone, tech. 80% 201-515-5 Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. The toxicological properties of this material have not been fully investigated. Skin: May cause skin irritation. The toxicological properties of this material have not been fully investigated. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 84-11-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Granules Color: orange-red Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 360 deg C Freezing/Melting Point: 209.00 - 211.00 C Autoignition Temperature: 630 deg C ( 1,166.00 deg F) Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Slightly soluble. Specific Gravity/Density: Molecular Formula: C14H8O2 Molecular Weight: 208.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stability unknown. Conditions to Avoid: Incompatible materials, dust generation, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke and fumes. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 84-11-7: SF7875000 LD50/LC50: Not available. Carcinogenicity: Phenanthrenequinone, tech. - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 22 Do not breathe dust. S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 84-11-7: No information available. Canada CAS# 84-11-7 is listed on Canada's NDSL List. CAS# 84-11-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 84-11-7 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 急性毒性： 小鼠腹腔LD50: 165mg/kg; 2、 慢性毒性/致癌性：小鼠皮肤TDL0：800 mg/kg/29W-C 3、 致畸性 沙门氏菌：30 umol/L； 枯草烟包杆菌：400ug/plate CHEMICAL IDENTIFICATION RTECS NUMBER : SF7875000 CHEMICAL NAME : Phenanthrenequinone CAS REGISTRY NUMBER : 84-11-7 BEILSTEIN REFERENCE NO. : 0608838 LAST UPDATED : 199710 DATA ITEMS CITED : 8 MOLECULAR FORMULA : C14-H8-O2 MOLECULAR WEIGHT : 208.22 WISWESSER LINE NOTATION : L B666 HVVJ HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 165 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 800 mg/kg/29W-C TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application MUTATION DATA TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 400 ug/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 66,337,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5889 No. of Facilities: 306 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 3675 (estimated) No. of Female Employees: 632 (estimated)

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H315-H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xi:Irritant
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36-S24/25-S22
• 危险品运输编码: UN3077
• WGK德国: 3
• RTECS号: SF7875000
• 包装等级: III
• 危险类别: 9
• 海关编码: 29146990

合成路线

上下游产品

上游产品  10
484-17-3 85-01-8 64440-29-5 938-24-9
93-58-3 93-89-0 5807-64-7 134-81-6
7509-44-6 2142-66-7
下游产品  10
467-69-6 486-25-9 1689-64-1 14205-64-2
14090-76-7 14140-04-6 947-73-9 863305-32-2
4445-30-1 947-84-2

制备

由菲氧化制成，有化学法及电解法。1.化学法用重铬酸钠（或钾）与菲在硫酸水溶液中氧化。2.电解氧化法电解液含三氧化铬120g/L、硫酸450g/L，含菲35g/L。阴极电流密度3.75A/cm2，电解液温度60-65℃，经电解8h后，过滤，得产品。

海关

海关编码	2914399090
中文概述	2914399090. 其他不含其他含氧基的芳香酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙酮报明包装
Summary	2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%