![三[N,N-双(三甲基硅烷)胺]钐(III)结构式](https://www.chemsrc.com/caspic/365/35789-01-6.png)
三[N,N-双(三甲基硅烷)胺]钐(III)结构式
|
常用名 | 三[N,N-双(三甲基硅烷)胺]钐(III) | 英文名 | samarium tris(hexamethyldisilazide) |
|---|---|---|---|---|
| CAS号 | 35789-01-6 | 分子量 | 631.51400 | |
| 密度 | N/A | 沸点 | 83-4ºC/1x10-4mmHg | |
| 分子式 | C18H54N3Si6Sm | 熔点 | 93-106ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 36 °F | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
| 中文名 | 三[N,N-二(三甲基甲硅烷基)酰胺]钐 |
|---|---|
| 英文名 | samarium tris(hexamethyldisilazide) |
| 英文别名 | 更多 |
| 沸点 | 83-4ºC/1x10-4mmHg |
|---|---|
| 熔点 | 93-106ºC(lit.) |
| 分子式 | C18H54N3Si6Sm |
| 分子量 | 631.51400 |
| 闪点 | 36 °F |
| 精确质量 | 632.21300 |
| PSA | 9.72000 |
| LogP | 7.26750 |
| 储存条件 | 2-8°C，密封，干燥，充气 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）： 2、 氢键供体数量：0 3、 氢键受体数量：3 4、 可旋转化学键数量：6 5、 互变异构体数量： 6、 拓扑分子极性表面积（TPSA）：3 7、 重原子数量：28 8、 表面电荷：0 9、 复杂度：297 10、同位素原子数量：0 11、确定原子立构中心数量：0 12、不确定原子立构中心数量：0 13、确定化学键立构中心数量：0 14、不确定化学键立构中心数量：0 15、共价键单元数量：4 |
| 符号 |
GHS02, GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H228-H261-H314 |
| 补充危害声明 | Reacts violently with water. |
| 警示性声明 | P210-P231 + P232-P280-P305 + P351 + P338-P310-P422 |
| 个人防护装备 | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| 危害码 (欧洲) | F: Flammable;C: Corrosive; |
| 风险声明 (欧洲) | R11 |
| 安全声明 (欧洲) | 16-26-36/37/39-43-45-7/8 |
| 危险品运输编码 | UN 3396 4.3/PG 2 |
|
Effect of concentration of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels.
J. Colloid. Interface Sci. 356(1) , 298-302, (2011) The surface free energy of a solid determines its surface and interfacial behavior in processes like wetting and adhesion which is crucial for silica aerogels in case of organic liquid absorption and ... |
|
|
A facile two-step dipping process based on two silica systems for a superhydrophobic surface.
Chem. Commun. (Camb.) 47(38) , 10761-3, (2011) A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, b... |
|
|
Trimethylsilylation of cellulose in ionic liquids.
Macromol. Biosci. 9(4) , 369-75, (2009) Trimethylsilylation of cellulose in different 1,3-dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a ... |
| Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C |
| samarium tris(hexamethylsilazide) |
| TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III) |
| MFCD03427097 |
| Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM |
| Tris[N,N-bis(trimethylsilyl)amide]samarium |
