… and Aminoacetyl Complexes of Palladium (II), Platinum (II), Iron (II) and Rhenium (I) with N??Phthaloyl as Amino Protecting Group and Mechanistic Studies on the …

…, K Polborn, S Schneiderbauer, M Beller…

Index: Enzmann, Armin; Eckert, Markus; Ponikwar, Walter; Polborn, Kurt; Schneiderbauer, Stefan; Beller, Matthias; Beck, Wolfgang European Journal of Inorganic Chemistry, 2004 , # 6 p. 1330 - 1340

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Citation Number: 23

Abstract

Abstract New aminomethyl and aminoacetyl complexes with N-phthaloyl as the amino protecting group were synthesised by oxidative addition of N-phthaloylmethyl or-acetyl halide to carbonylmetallates or to Pd (PPh 3) 4 or [Pt (C 2 H 4)(PPh 3) 2] to give [Re {C (O) CH 2 N-phthaloyl}(CO) 5](1),[FeCp (CH 2 N-phthaloyl)(CO) 2](2),[FeCp {C (O) CH 2 N- phthaloyl}(CO) 2](3), trans-[PdBr (CH 2 N-phthaloyl)(PPh 3) 2](4) and trans-[Pd {C (O) CH ...