Highly efficient Pd-catalyzed carbonylative cross-coupling reactions with tetraorganoindates

SW Lee, K Lee, D Seomoon, S Kim, H Kim…

Index: Lee, Sung Wook; Lee, Kooyeon; Seomoon, Dong; Kim, Sundae; Kim, Hyunseok; Kim, Hyun; Shim, Eunkyong; Lee, Miae; Lee, Seokju; Kim, Misook; Lee, Phil Ho Journal of Organic Chemistry, 2004 , vol. 69, # 14 p. 4852 - 4855

Full Text: HTML

Citation Number: 67

Abstract

Tetraorganoindates, which were prepared easily from the reaction of 1 equiv of InCl3 with 4 equiv of organometallics, could be employed as effective nucleophilic cross-coupling partners in Pd-catalyzed carbonylative cross-coupling reactions with a variety of organic electrophiles. The present method gave unsymmetrical ketones and 1, 4-diacylbenzenes in good yields with highly efficient transfer of almost all the organic groups attached to the ...