Annulation reactions with iron (III) chloride: oxidation of imines

…, D Nanni, A Tundo, G Zanardi, F Ruggieri

Index: Leardini, Rino; Nanni, Daniele; Tundo, Antonio; Zanardi, Giuseppe; Ruggieri, Fabrizio Journal of Organic Chemistry, 1992 , vol. 57, # 6 p. 1842 - 1848

Full Text: HTML

Citation Number: 54

Abstract

Aromatic imines react with phenylacetylene or styrene in an acetonitrile solution of iron (II1) chloride to give quinolines 3 or their tetrahydro derivatives 11 together with variable amounts of products 4 arising from the reduction of the imines. The initial step appears to be a one-electron oxidation to generate iron (I1) and an imine radical cation. When the reactions are carried out in the presence of stoichiometric amounts of tetrachloro- ...

 Related Synthetic Route

~33%

Learn More

~28%

Learn More

~24%

Learn More

~10%

Learn More

~59%

Learn More

~83%

Learn More

~29%

Learn More

~48%

Learn More

~51%

Detail Learn More

~52%

Learn More

~65%

Learn More

~55%

Learn More

~22%

Learn More

~68%

Detail Learn More

~23%

Detail Learn More

~%

Learn More

~43%

Learn More

~20%

Learn More

~19%

Learn More

~18%

Detail Learn More

~%

Learn More

~35%

Learn More

~29%

Learn More

~15%

Learn More