Synthesis of S-thioacyl dithiophosphates, efficient and chemoselective thioacylating agents

L Doszczak, J Rachon

Index: Doszczak, Leszek; Rachon, Janusz Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 10 p. 1271 - 1279

Full Text: HTML

Citation Number: 18

Abstract

Easily available acyl dithiophosphates are not stable and isomerise reversibly to O-thioacyl monothiophosphates, especially when subjected to heating. Much slower but probably irreversible isomerisation to S-thioacyl monothiophosphates occurs. Since equilibrium states are established and S-thioacyl (mono) thiophosphates form slowly, reaction mixtures contain generally both thioacylating and acylating agents, and consequently cannot be used for ...

 Related Synthetic Route

~96%

Learn More

~30%

Learn More

~89%

Learn More

~92%

Learn More

~%

Learn More

~%

Learn More

~%

Learn More

~90%

Learn More

~10%

Learn More

~75%

Learn More

~92%

Learn More

~93%

Learn More

~14%

Learn More

~83%

Learn More

~%

Learn More

~%

Learn More

~%

Learn More

~79%

Learn More

~93%

Learn More

~82%

Learn More

~96%

Learn More

~76%

Learn More

~98%

Learn More

~61%

Learn More