e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Supramolecular allosteric cofacial porphyrin complexes

CG Oliveri, NC Gianneschi, SBT Nguyen…

Index: Oliveri, Christopher G.; Gianneschi, Nathan C.; Nguyen, SonBinh T.; Mirkin, Chad A.; Stern, Charlotte L.; Wawrzak, Zdzislaw; Pink, Maren Journal of the American Chemical Society, 2006 , vol. 128, # 50 p. 16286 - 16296

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Citation Number: 88

Abstract

Nature routinely uses cooperative interactions to regulate cellular activity. For years, chemists have designed synthetic systems that aim toward harnessing the reactivity common to natural biological systems. By learning how to control these interactions in situ, one begins to allow for the preparation of man-made biomimetic systems that can efficiently mimic the interactions found in Nature. To this end, we have designed a synthetic protocol ...

2-(4-bromophenyl)sulfanylethyl-diphenylphosphane Structure

2-(4-bromopheny...

~92%

2-(4-bromophenyl)sulfanylethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-(4-bromopheny...

2-chloroethyl-diphenyl-phosphane Structure

2-chloroethyl-d...

~%

2-(4-bromophenyl)sulfanylethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-(4-bromopheny...

4-Bromothiophenol Structure

4-Bromothiophenol

~%

2-(4-bromophenyl)sulfanylethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-(4-bromopheny...

2-(4-bromophenyl)sulfanylethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-(4-bromopheny...

N,N-Dimethylformamide Structure

N,N-Dimethylfor...

~86%

4-(2-diphenylphosphinothioylethylsulfanyl)benzaldehyde Structure

4-(2-diphenylph...

2-chloroethyl-diphenyl-phosphane Structure

2-chloroethyl-d...

~%

4-(2-diphenylphosphinothioylethylsulfanyl)benzaldehyde Structure

4-(2-diphenylph...

4-Bromothiophenol Structure

4-Bromothiophenol

~%

4-(2-diphenylphosphinothioylethylsulfanyl)benzaldehyde Structure

4-(2-diphenylph...

2-(4-bromophenyl)sulfanylethyl-diphenylphosphane Structure

2-(4-bromopheny...

~%

4-(2-diphenylphosphinothioylethylsulfanyl)benzaldehyde Structure

4-(2-diphenylph...

1,3-Propanedithiol Structure

1,3-Propanedithiol

4-(2-Chloroethoxy)benzaldehyde Structure

4-(2-Chloroetho...

~76%

2-[4-(2-chloroethoxy)phenyl]-1,3-dithiane Structure

2-[4-(2-chloroe...

4-hydroxybenzaldehyde Structure

4-hydroxybenzal...

~%

2-[4-(2-chloroethoxy)phenyl]-1,3-dithiane Structure

2-[4-(2-chloroe...

2-[4-(2-chloroethoxy)phenyl]-1,3-dithiane Structure

2-[4-(2-chloroe...

potassium diphenylphosphide Structure

potassium diphe...

~87%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenylphosphane Structure

2-[4-(1,3-dithi...

4-(2-Chloroethoxy)benzaldehyde Structure

4-(2-Chloroetho...

~%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenylphosphane Structure

2-[4-(1,3-dithi...

4-hydroxybenzaldehyde Structure

4-hydroxybenzal...

~%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenylphosphane Structure

2-[4-(1,3-dithi...

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenylphosphane Structure

2-[4-(1,3-dithi...

~94%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-[4-(1,3-dithi...

2-[4-(2-chloroethoxy)phenyl]-1,3-dithiane Structure

2-[4-(2-chloroe...

~%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-[4-(1,3-dithi...

4-(2-Chloroethoxy)benzaldehyde Structure

4-(2-Chloroetho...

~%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-[4-(1,3-dithi...

4-hydroxybenzaldehyde Structure

4-hydroxybenzal...

~%

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-[4-(1,3-dithi...

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenyl-sulfanylidene-λ5-phosphane Structure

2-[4-(1,3-dithi...

~90%

4-(2-diphenylphosphinothioylethoxy)benzaldehyde Structure

4-(2-diphenylph...

2-[4-(2-chloroethoxy)phenyl]-1,3-dithiane Structure

2-[4-(2-chloroe...

~%

4-(2-diphenylphosphinothioylethoxy)benzaldehyde Structure

4-(2-diphenylph...

2-[4-(1,3-dithian-2-yl)phenoxy]ethyl-diphenylphosphane Structure

2-[4-(1,3-dithi...

~%

4-(2-diphenylphosphinothioylethoxy)benzaldehyde Structure

4-(2-diphenylph...

4-(2-Chloroethoxy)benzaldehyde Structure

4-(2-Chloroetho...

~%

4-(2-diphenylphosphinothioylethoxy)benzaldehyde Structure

4-(2-diphenylph...

4-hydroxybenzaldehyde Structure

4-hydroxybenzal...

~%

4-(2-diphenylphosphinothioylethoxy)benzaldehyde Structure

4-(2-diphenylph...