Organometallics

Phenols as Starting Materials for the Synthesis of Arylstannanes via SRN11

AB Chopa, MT Lockhart, VB Dorn

Index: Chopa, Alicia B.; Lockhart, Maria T.; Dorn, Viviana B. Organometallics, 2002 , vol. 21, # 7 p. 1425 - 1429

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Citation Number: 37

Abstract

Triorganostannyl anions have proved to be excellent nucleophiles in S RN 1 reactions. 5 Application of these reactions to the synthesis of arylstannanes is currently in progress in our laboratory. We have recently described the photostimulated reactions of a number of haloarenes and haloheteroarenes with triphenylstannyl anions in dimethyl sulfoxide (DMSO) and acetonitrile (ACN) as solvents. 6 The photostimulated reactions of 1-chloronaphthalene, 2- and ...