Tetrahedron Letters

Reactions of nitrile oxides with 2-lithio-1, 3-dithianes synthesis of α-diketones

T Yamamori, I Adachi

Index: Yamamori, Teruo; Adachi, Ikuo Tetrahedron Letters, 1980 , vol. 21, p. 1747 - 1750

Full Text: HTML

Citation Number: 10

Abstract

This document does not have an outline. ... JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. ... Author links open the overlay panel. Numbers correspond to the affiliation list which can be exposed by using the show more link. ... Nitrile oxides (2) were treated with 2-lithio-1,3-dithianes (4) to give in good yields masked ketoximes (5), new synthetic tools for a α-diketones. ... Treatment of la with n-butyllithium in THF ...

 Related Synthetic Route
N/A Structure

74954-96-4

N/A

~79%

1-(2-chlorophenyl)-2-phenylethane-1,2-dione Structure

34082-45-6

1-(2-chlorophen...

1,3-Dithiane, 2-phenyl- Structure

5425-44-5

1,3-Dithiane, 2...

~%

1-(2-chlorophenyl)-2-phenylethane-1,2-dione Structure

34082-45-6

1-(2-chlorophen...

2-chlorobenzonitrile oxide Structure

49660-38-0

2-chlorobenzoni...

~%

1-(2-chlorophenyl)-2-phenylethane-1,2-dione Structure

34082-45-6

1-(2-chlorophen...

2-CHLOROBENZAMIDEOXIME Structure

29568-74-9

2-CHLOROBENZAMI...

~%

1-(2-chlorophenyl)-2-phenylethane-1,2-dione Structure

34082-45-6

1-(2-chlorophen...

2-CHLOROBENZAMIDEOXIME Structure

29568-74-9

2-CHLOROBENZAMI...

~%

2-chlorobenzonitrile oxide Structure

49660-38-0

2-chlorobenzoni...

benzonitrile oxide Structure

873-67-6

benzonitrile oxide

~%

1,2-Ethanedione,1-[4-(dimethylamino)phenyl]-2-phenyl- Structure

22711-20-2

1,2-Ethanedione...

Alpha-Chlorobenzaldoxime Structure

698-16-8

Alpha-Chloroben...

~%

1,2-Ethanedione,1-[4-(dimethylamino)phenyl]-2-phenyl- Structure

22711-20-2

1,2-Ethanedione...

N/A Structure

74955-11-6

N/A

~87%

1,2-Ethanedione,1-(4-hydroxyphenyl)-2-phenyl- Structure

38469-73-7

1,2-Ethanedione...

benzonitrile oxide Structure

873-67-6

benzonitrile oxide

~%

1,2-Ethanedione,1-(4-hydroxyphenyl)-2-phenyl- Structure

38469-73-7

1,2-Ethanedione...

Alpha-Chlorobenzaldoxime Structure

698-16-8

Alpha-Chloroben...

~%

1,2-Ethanedione,1-(4-hydroxyphenyl)-2-phenyl- Structure

38469-73-7

1,2-Ethanedione...

(Z)-(2-(4-chlorophenyl)-1,3-dithian-2-yl)(phenyl)methanone oxime Structure

74955-09-2

(Z)-(2-(4-chlor...

~71%

4-chlorobenzil Structure

22711-23-5

4-chlorobenzil

(Z)-(2-chlorophenyl)(2-(4-methoxyphenyl)-1,3-dithian-2-yl)methanone oxime Structure

74954-98-6

(Z)-(2-chloroph...

~74%

1-(2-chlorophenyl)-2-(4-methoxyphenyl)ethane-1,2-dione Structure

41841-01-4

1-(2-chlorophen...

4-Methoxybenzaldehyde trimethylenedithioacetal Structure

24588-72-5

4-Methoxybenzal...

~%

1-(2-chlorophenyl)-2-(4-methoxyphenyl)ethane-1,2-dione Structure

41841-01-4

1-(2-chlorophen...

2-chlorobenzonitrile oxide Structure

49660-38-0

2-chlorobenzoni...

~%

1-(2-chlorophenyl)-2-(4-methoxyphenyl)ethane-1,2-dione Structure

41841-01-4

1-(2-chlorophen...

2-CHLOROBENZAMIDEOXIME Structure

29568-74-9

2-CHLOROBENZAMI...

~%

1-(2-chlorophenyl)-2-(4-methoxyphenyl)ethane-1,2-dione Structure

41841-01-4

1-(2-chlorophen...

(Z)-(2-(4-methoxyphenyl)-1,3-dithian-2-yl)(phenyl)methanone oxime Structure

74955-10-5

(Z)-(2-(4-metho...

~92%

1,2-Ethanedione,1-(4-methoxyphenyl)-2-phenyl- Structure

22711-21-3

1,2-Ethanedione...

benzonitrile oxide Structure

873-67-6

benzonitrile oxide

~%

1,2-Ethanedione,1-(4-methoxyphenyl)-2-phenyl- Structure

22711-21-3

1,2-Ethanedione...

Alpha-Chlorobenzaldoxime Structure

698-16-8

Alpha-Chloroben...

~%

1,2-Ethanedione,1-(4-methoxyphenyl)-2-phenyl- Structure

22711-21-3

1,2-Ethanedione...


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