Palladium??Catalyzed Reductive Carbonylation of Aryl Bromides with Phosphinite Ligands

H Neumann, R Kadyrov, XF Wu…

Index: Neumann, Helfried; Kadyrov, Renat; Wu, Xiao-Feng; Beller, Matthias Chemistry - An Asian Journal, 2012 , vol. 7, # 10 p. 2213 - 2216

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Citation Number: 16

Abstract

Aromatic aldehydes are an important class of compounds, that are widely used as building blocks in all areas of chemistry.[1] Traditionally, aromatic aldehydes were synthesized by Vielsmeier–Haag, Gattermann–Koch, Reimer–Tiemann, and Duff reactions. However, these reactions use high amounts of reagents and generate waste and side products.[2] Other synthetic strategies include the reduction of acid chlorides under an atmosphere of ...

 Related Synthetic Route
carbon monoxide Structure

201230-82-2

carbon monoxide

4-Bromobenzaldehyde Structure

1122-91-4

4-Bromobenzaldehyde

~70%

Terephthalaldehyde Structure

623-27-8

Terephthalaldehyde

4-Bromochlorobenzene Structure

106-39-8

4-Bromochlorobenzene

carbon monoxide Structure

201230-82-2

carbon monoxide

~95%

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

3-Bromothiophene Structure

872-31-1

3-Bromothiophene

carbon monoxide Structure

201230-82-2

carbon monoxide

~84%

3-Thiophenecarboxaldehyde Structure

498-62-4

3-Thiophenecarb...

carbon monoxide Structure

201230-82-2

carbon monoxide

4-Bromoveratrole Structure

2859-78-1

4-Bromoveratrole

~70%

veratraldehyde Structure

120-14-9

veratraldehyde

5-Bromo-1-benzothiophene Structure

7342-82-7

5-Bromo-1-benzo...

carbon monoxide Structure

201230-82-2

carbon monoxide

~63%

1-Benzothiophene-3-carbaldehyde Structure

5381-20-4

1-Benzothiophen...

bromoanisole Structure

578-57-4

bromoanisole

carbon monoxide Structure

201230-82-2

carbon monoxide

~66%

o-Anisaldehyde Structure

135-02-4

o-Anisaldehyde

carbon monoxide Structure

201230-82-2

carbon monoxide

2,4,6-Trimethylbromobenzene Structure

576-83-0

2,4,6-Trimethyl...

~34%

Mesitaldehyde Structure

487-68-3

Mesitaldehyde

2-Bromonaphthalene Structure

580-13-2

2-Bromonaphthalene

carbon monoxide Structure

201230-82-2

carbon monoxide

~89%

2-Naphthaldehyde Structure

66-99-9

2-Naphthaldehyde

carbon monoxide Structure

201230-82-2

carbon monoxide

4-Bromo-N,N-dimethylaniline Structure

586-77-6

4-Bromo-N,N-dim...

~92%

p-Dimethylaminobenzaldehyde Structure

100-10-7

p-Dimethylamino...

1-Bromo-4-tert-butylbenzene Structure

3972-65-4

1-Bromo-4-tert-...

carbon monoxide Structure

201230-82-2

carbon monoxide

~97%

p-t-Butylbenzaldehyde Structure

939-97-9

p-t-Butylbenzal...

carbon monoxide Structure

201230-82-2

carbon monoxide

1-Bromonaphthalene Structure

90-11-9

1-Bromonaphthalene

~87%

naphthal Structure

66-77-3

naphthal

carbon monoxide Structure

201230-82-2

carbon monoxide

4-Bromobiphenyl Structure

92-66-0

4-Bromobiphenyl

~91%

4-Biphenylcarbaldehyde Structure

3218-36-8

4-Biphenylcarba...

carbon monoxide Structure

201230-82-2

carbon monoxide

1-Bromo-4-fluorobenzene Structure

460-00-4

1-Bromo-4-fluor...

~90%

4-Fluorobenzaldehyde Structure

459-57-4

4-Fluorobenzaldehyde

m-Bromoanisole Structure

2398-37-0

m-Bromoanisole

carbon monoxide Structure

201230-82-2

carbon monoxide

~81%

m-Anisaldehyde Structure

591-31-1

m-Anisaldehyde

carbon monoxide Structure

201230-82-2

carbon monoxide

3-Bromotoluene Structure

591-17-3

3-Bromotoluene

~88%

m-Tolualdehyde Structure

620-23-5

m-Tolualdehyde


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