Inorganic Chemistry

Fluorination of boron chlorides and boron bromides by reaction with bis (trifluoromethyl) mercury, trichlorofluoromethane, or tribromofluoromethane: synthesis of …

DA Saulys, J Castillo, JA Morrison

Index: Saulys, D. A; Castillo, J.; Morrison, J. A. Inorganic Chemistry, 1989 , vol. 28, p. 1619 - 1624

Full Text: HTML

Citation Number: 6

Abstract

Discussion The planarity condition calculations shown in Table VI1 were used in calculating molecular structure parameters of C2B5H6F, which are compared with those of the parent C2B5H7 structure in Table VIII. It is seen that slight increases in bond lengths occur upon fluorination at the B5 site. The B,-B7 distance is 0.013 A larger in the fluoro derivative. Due to the larger than usual uncertainties in the locations of the B5 and B, atoms, some structural ...