The Journal of Organic Chemistry

Reaction of singlet oxygen with enamino carbonyl systems. A general method for the synthesis of. alpha.-keto derivatives of lactones, esters, amides, lactams, and …

HH Wasserman, JL Ives

Index: Wasserman, Harry H.; Ives, Jeffrey L. Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3573 - 3580

Full Text: HTML

Citation Number: 79

Abstract

-_ _ conversion of a ketone to an a-diketone, for example, has been employed in the synthesis of colchicine, ls strychnine, lb and other natural products. There have been important applications of a-keto lactam formation in synthesis, ranging from the preparation of senecio2 and vasicine al-kaloid~~ to the synthesis of P-lactams4 and derivatives of penams and cephams. 6 In addition, there is intrinsic

~92%

~95%

~81%

~71%

~78%

~64%

~58%

~93%

~95%

~84%

~80%

Substituted 2-hydroxy-1, 2-dihydropyrrol-3-ones: Fluorescent...

[Chen, Peng; Wiesler, Donald; Chmelik, Josef; Novotny, Milos Chemical Research in Toxicology, 1996 , vol. 9, # 6 p. 970 - 979]

Novel synthesis of 2-oxo-4-phenyl-3-butynoic acid, a new inh...

[Journal of Organic Chemistry, , vol. 59, # 19 p. 5763 - 5766]

Synthesis and Reactivity of α-and β-Chloro-α-phenylselanyl E...

[Lebarillier, Loic; Outurquin, Francis; Paulmier, Claude Tetrahedron, 2000 , vol. 56, # 38 p. 7495 - 7502]

Synthesis and reactivity of β-phenylselanyl α-oxoesters

[Boivin, Stephane; Outurquin, Francis; Paulmier, Claude Tetrahedron, 1997 , vol. 53, # 49 p. 16767 - 16782]

Phase transfer catalyzed hydrolysis of thioacetals using pyr...

[Bates, Gordon S.; O'Doherty, James Journal of Organic Chemistry, 1981 , vol. 46, # 8 p. 1745 - 1747]