Tetrahedron letters

Biomimetic oxidation of metribuzin with hydrogen peroxide catalyzed by 5, 10, 15, 20-tetraarylporphyrinatoiron (III) chlorides

SMS Chauhan, P Kumari

Index: Chauhan, Shive M.S.; Kumari, Pratibha Tetrahedron Letters, 2007 , vol. 48, # 29 p. 5035 - 5038

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Citation Number: 15

Abstract

The biomimetic oxidation of metribuzin, a pre-and post-emergence herbicide with hydrogen peroxide catalyzed by 5, 10, 15, 20-tetraarylporphyrinatoiron (III) chlorides [TAPFe (III) Cl], has been studied yielding 6-t-butyl-3-methylthio-1, 2, 4-triazine-5 (4H)-one, 4-amino-6-t- butyl-3, 5 (2H, 4H)-dione and 6-t-butyl-1, 2, 4-triazin-3, 5 (2H, 4H)-dione under various reaction conditions.