Fluorination of polyhalogenated unsaturated compounds with vanadium pentafluoride

…, AA Avramenko, GG Furin, VA Krasilnikov…

Index: Bardin, V. V.; Avramenko, A. A.; Furin, G. G.; Krasilnikov, V. A.; Karelin, A. I.; et al. Journal of Fluorine Chemistry, 1990 , vol. 49, # 3 p. 385 - 400

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Citation Number: 11

Abstract

Vanadium pentafluoride reaots with polyfluorinated and polychlorinated olefins, alkadienes, cycloalkenes and cyclo- dienes in CFC13 or without a solvent at -25' to IOO'C, forming products of addltlon of two fluorine atoms across the C=C bond. ... Earlier we have reported fluorination of hexafluorobenze- ne, deoafluorodiphenyl, ootafluoronaphthalene [ll, ... 0022-1139/90/$3.50 0 Elsevler Sequola/Prlnted in The Netherlands ... Fluorination of terminal fluoroolefins by ...

~60%

~88%

~80%

~41%

~72%

~94%

~27%

~72%

~65%

~61%

~45%

~79%

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