Enzymic aldol condensation/isomerization as a route to unusual sugar derivatives

JR Durrwachter, DG Drueckhammer…

Index: Durrwachter,J.; Drueckhammer,D.; Nozaki,K. Journal of the American Chemical Society, 1986 , vol. 108, p. 7812

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Citation Number: 119

Abstract

Abstract: Preparative enzymatic synthesis of several unusual hexoketose and hexoaldose derivatives using fructose bisphosphate aldolase and glucose isomerase as catalysts has been developed. Fructose bisphosphate aldolase catalyzes a stereospecific aldol condensation between dihydroxyacetone phosphate and a number of aldehydes to form ketose 1-phosphates which upon removal of the phosphate groups by hydrolysis are ...

~39%

… smallest vicinal tricarbonyl compound as a monohydrate and...

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Efficient preparation of α-ketoacetals

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Highly Active and Recyclable Sn??MWW Zeolite Catalyst for Su...

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Reactions of alcohols with α-alkoxyacroleins at room tempera...

[Russian Chemical Bulletin, , vol. 47, # 12 p. 2422 - 2425]