Chemistry–A European Journal

Dichloro??Bis (aminophosphine) Complexes of Palladium: Highly Convenient, Reliable and Extremely Active Suzuki–Miyaura Catalysts with Excellent Functional …

JL Bolliger, CM Frech

Index: Bolliger, Jeanne L.; Frech, Christian M. Chemistry - A European Journal, 2010 , vol. 16, # 13 p. 4075 - 4081

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Citation Number: 49

Abstract

Abstract Dichloro-bis (aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent Suzuki–Miyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed their formation to be controlled. Dichlorobis [1-(dicyclohexylphosphanyl) piperidine] palladium (3), the most active catalyst of the investigated systems, is a highly convenient, ...