The Journal of Organic Chemistry

Alkali metal salts of perfluorinated complex anions. Effective reagents for nucleophilic fluorination

O Farooq, GVD Tiers

Index: Farooq, Omar; Tiers, George V. D. Journal of Organic Chemistry, 1994 , vol. 59, # 8 p. 2122 - 2124

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Citation Number: 20

Abstract

Alkali metal salts of perfluorinated complex anions were used to effect halogen-exchange fluorination in organohalosilanes both in the presence and absence of solvent. By the use of salts of perfluorinated “non-nucleophilic” anions in a high-boiling multifunctional etheral solvent, organofluorosilanes have been conveniently prepared in high yields.