Synthesis

Palladium-catalyzed silane/siloxane reductions in the one-pot conversion of nitro compounds into their amines, hydroxylamines, amides, sulfonamides, and …

RJ Rahaim Jr, RE Maleczka Jr

Index: Synthesis, , # 19 p. 3316 - 3340

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Citation Number: 29

Abstract

... Scheme 1 Nitro compounds: versatile building blocks in synthesis. ... On the other hand, the presence of phosphine, either added as Ph 3 P or in the form of ... We assume phosphine ligands disrupt the dispersion of Pd throughout the PMHS matrix [19] and as a consequence disrupt ...