Synthesis, Structure, and Reactivity of Anionic sp2–sp3 Diboron Compounds: Readily Accessible Boryl Nucleophiles

…, U Radius, Z Lin, C Kleeberg, TB Marder

Index: Kleeberg, Christian; Dang, Li; Lin, Zhenyang; Marder, Todd B. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5350 - 5354 Angewandte Chemie, 2009 , vol. 121, p. 5454 - 5458

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Citation Number: 32

Abstract

Abstract Lewis base adducts of tetra-alkoxy diboron compounds, in particular bis (pinacolato) diboron (B 2 pin 2), have been proposed as the active source of nucleophilic boryl species in metal-free borylation reactions. We report the isolation and detailed