The Journal of Organic Chemistry

Deoxygenation of sulfoxides promoted by electrophilic silicon reagents: preparation of aryl-substituted sulfonium salts

RD Miller, AF Renaldo, H Ito

Index: Miller, R. D.; Renaldo, A. F.; Ito, H. Journal of Organic Chemistry, 1988 , vol. 53, # 23 p. 5571 - 5573

Full Text: HTML

Citation Number: 40

Abstract

2. alkylation of the corresponding sulfides by a wide variety of common alkylating reagents. Unfortunately, this technique is less successful for the preparation of sterically hindered or polyaryl-substituted materials. ld The preparation of sulfonium salts of this type usually requires the use of metallic complexing reagents2 and/or the use of powerful electrophilic reagent^.^ The latter is epitomized by the sulfide arylation reaction, which requires the use ...