ChemCatChem

Palladium??Catalyzed C H ortho Arylation of Benzoic Acids with Diaryliodonium Salts in Water

Z Wu, S Chen, C Hu, Z Li, H Xiang, X Zhou

Index: Wu, Zhiqing; Chen, Si; Hu, Chenxu; Li, Zhengkai; Xiang, Haifeng; Zhou, Xiangge ChemCatChem, 2013 , vol. 5, # 10 p. 2839 - 2842

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Citation Number: 20

Abstract

Palladium-catalyzed CÀC bond-formation reactions between aryl halides or triflates and organometallic reagents are among the most useful methods to construct biaryls, which are usually structural motifs found in important nature products, pharmaceuticals, and organic materials.[1] The corresponding organometallic nucleophilic starting materials, however, are often not commercially available and sometimes lead to the formation of undesired side ...