Journal of the American Chemical Society

Synthesis of nonsubstituted anilines from molecular nitrogen via transmetalation of arylpalladium complex with titanium-nitrogen fixation complexes

K Hori, M Mori

Index: Hori; Mori Journal of the American Chemical Society, 1998 , vol. 120, # 30 p. 7651 - 7652

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Citation Number: 51

Abstract

Since Migita1 succeeded in synthesizing disubstituted aniline derivatives from arylpalladium complex and dialkylstannane, a method for synthesizing mono-and disubstituted aniline derivatives from aryl halides using palladium catalyst has been established by the ingenious studies of Buchwald and Hartwig. 2 However, synthesis of nonsubstituted aniline derivatives from arylpalladium complex was not known because we must use NH3 for that purpose. ...