Phenyliodonium bis (phenylsulfonyl) methylide, a new hypervalent iodonium ylide

L Hadjiarapoglou, S Spyroudis…

Index: Hadjiarapoglou, Lazaros; Spyroudis, Spyros; Varvoglis, Anastasios Journal of the American Chemical Society, 1985 , vol. 107, # 24 p. 7178 - 7179

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Citation Number: 58

Abstract

Compounds with a sulfonyl group in general1 and gem-disulfones in particular2 are increasingly attracting attention for their potential in organic synthesis. At the same time, iodonium ylides are being established as a class of ylides of synthetic and mechanistic intere~ t.~ We report the synthesis and chemistry of a new type of iodonium ylide, the carbanion moiety of which is a 6-disulfonyl group, Le., phenyliodonium bis ( ...