Diarylated Ethanones from Mo (CO) 6??Mediated and Microwave??Assisted Palladium??Catalysed Carbonylative Negishi Cross??Couplings

HV Motwani, M Larhed

Index: Motwani, Hitesh V.; Larhed, Mats European Journal of Organic Chemistry, 2013 , # 22 p. 4729 - 4733

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Citation Number: 2

Abstract

Abstract Two protocols for palladium-catalysed carbonylative Negishi cross-couplings were developed for aryl iodides and aryl bromides. The two main breakthroughs were that molybdenum hexacarbonyl [Mo (CO) 6] could be used as a solid in situ source of CO, and that controlled microwave irraditaion could be used for heating. Consequently, the reactions were safe (in contrast to when CO gas was used) and fast (in comparison to when ...

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