The thermal addition reactions of cycloheptatriene with aromatic p-quinones

A Mori, H Mametsuka, H Takeshita

Index: Mori, Akira; Mametsuka, Hiroaki; Takeshita, Hitoshi Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 2072 - 2077

Full Text: HTML

Citation Number: 5

Abstract

Thermal addition reactions of cycloheptatriene with several aromatic p-quinones gave the Diels-Alder adducts as minor products; the most characteristic feature was the formation of the vic-ditropylation products. The mechanism of their formation was clarified to be a sequential ene-reaction and dehydrogenation by means of chemical conversion from the isolated intermediates. Several new other additions, eg, successive Diels-Alder reactions, ...

 Related Synthetic Route
2,6-dimethyl-p-benzoquinone Structure

527-61-7

2,6-dimethyl-p-...

~5%

7-(1-cyclohepta-2,4,6-trienyl)cyclohepta-1,3,5-triene Structure

831-18-5

7-(1-cyclohepta...

2,6-DIMETHYLHYDROQUINONE Structure

654-42-2

2,6-DIMETHYLHYD...

2-(cyclohepta-2,4,6-trien-1-yl)-3,5-dimethylcyclohexa-2,5-diene-1,4-dione Structure

60457-35-4

2-(cyclohepta-2...

Cycloheptatriene Structure

544-25-2

Cycloheptatriene

1,4-Benzoquinone Structure

106-51-4

1,4-Benzoquinone

~1%

7-(1-cyclohepta-2,4,6-trienyl)cyclohepta-1,3,5-triene Structure

831-18-5

7-(1-cyclohepta...

Structure

60457-25-2

Detail
2,6-dimethyl-p-benzoquinone Structure

527-61-7

2,6-dimethyl-p-...

Cycloheptatriene Structure

544-25-2

Cycloheptatriene

~5%

7-(1-cyclohepta-2,4,6-trienyl)cyclohepta-1,3,5-triene Structure

831-18-5

7-(1-cyclohepta...

2,6-DIMETHYLHYDROQUINONE Structure

654-42-2

2,6-DIMETHYLHYD...

Detail
2-Methylcyclohexa-2,5-diene-1,4-dione Structure

553-97-9

2-Methylcyclohe...

Cycloheptatriene Structure

544-25-2

Cycloheptatriene

~2%

7-(1-cyclohepta-2,4,6-trienyl)cyclohepta-1,3,5-triene Structure

831-18-5

7-(1-cyclohepta...

5,6-di(cyclohepta-2,4,6-trien-1-yl)-2-methylcyclohex-2-ene-1,4-dione Structure

60457-31-0

5,6-di(cyclohep...

Detail
Cycloheptatriene Structure

544-25-2

Cycloheptatriene

1,4-naphthoquinone Structure

130-15-4

1,4-naphthoquinone

~5%

2-cyclohepta-2,4,6-trien-1-yl-2,3-dihydronaphthalene-1,4-dione Structure

61609-27-6

2-cyclohepta-2,...

N/A Structure

61609-24-3

N/A

Detail
2-cyclohepta-2,4,6-trien-1-yl-2,3-dihydronaphthalene-1,4-dione Structure

61609-27-6

2-cyclohepta-2,...

~72%

2-cyclohepta-2,4,6-trien-1-ylnaphthalene-1,4-dione Structure

61609-30-1

2-cyclohepta-2,...

Cycloheptatriene Structure

544-25-2

Cycloheptatriene

~%

2-cyclohepta-2,4,6-trien-1-ylnaphthalene-1,4-dione Structure

61609-30-1

2-cyclohepta-2,...

1,4-naphthoquinone Structure

130-15-4

1,4-naphthoquinone

~%

2-cyclohepta-2,4,6-trien-1-ylnaphthalene-1,4-dione Structure

61609-30-1

2-cyclohepta-2,...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved