Journal of the American Chemical Society

Characterization of Functional Groups by Nuclear Magnetic Resonance. I. Classification of Alcohols from the Fluorine-19 Spectra of Trifluoroacetates1

SL Manatt

Index: Manatt,S.L. Journal of the American Chemical Society, 1966 , vol. 88, p. 1323 - 1324

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Citation Number: 35

Abstract

We wish to describe an nmr scheme for classification of hydroxyl compounds which in our hands has generally proved to be more reliable and informative than other recently described nmr techniques. Because a number of functional groups can be acetylated, we initially considered that the acetate group might be a useful nmr probe for classification purposes. Unfortunately, the differences in chemical shift between acetate groups of ...