Russian Journal of General Chemistry

Direct synthesis of 1-organylsilatranes from organyltrichlorosilanes and tris (2-hydroxyethyl) amine

MG Voronkov, GA Kuznetsova

Index: Voronkov; Kuznetsova Russian Journal of General Chemistry, 2009 , vol. 79, # 5 p. 925 - 927

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Abstract

Abstract A direct method of synthesis of 1-organylsilatranes by the reaction of organyltrichlorosilanes with tris (2-hydroxyethyl) amine was developed. 1-Organylsilatranes RSi (OCH 2 CH 2) 3 N with R= Me, Et, Ph, ClCH 2, ICH 2, Cl (CH 2) 3 were prepared by this method in up to 72% yield.