Manganese (II and III)-Mediated Synthesis of Cyclic Peroxides from Alkenes, Active Methylene Compounds, and Molecular Oxygen.

…, T Yamada, H Nishino, K Kurosawa

Index: Qian, Chang-Yi; Yamada, Takashi; Nishino, Hiroshi; Kurosawa, Kazu Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 5 p. 1371 - 1378

Full Text: HTML

Citation Number: 43

Abstract

The reaction of 1, 1-diphenylethene, 1, 1-bis (4-chlorophenyl) ethene, 1, 1-bis (4- methylphenyl) ethene, 1, 1-bis (4-methoxyphenyl) ethene, and 1, 1-bis (4-fluorophenyl) ethene with 2-methyl-1, 3-cyclohexanedione, 2-methyl-1, 3-cyclopentanedione, 2- acetylcyclohexanone, ethyl 2-acetyl-3-oxobutanoate, 3-methyl-2, 4-pentanedione, 1, 3- cyclohexanedione, and 2, 4-pentanedione in the presence of Mn (OAc) 2 and molecular ...