On the synthesis of geometric isomers of 2??methyl (or phenyl)??4??[α??arylethylidene]??5 (4H)??oxazolones

…, D Villegas, MD Diaz, E Meléndez

Index: Cativiela, C.; Diaz de Villegas, M. D.; Melendez, E. Journal of Heterocyclic Chemistry, 1985 , vol. 22, p. 1655 - 1657

Full Text: HTML

Citation Number: 14

Abstract

Abstract Several Z-2-methyl (or phenyl)-4-[α-arylethylidene]-5 (4H)-oxazolones 3Z, 4Z were prepared. The results obtained were compared by diazomethane insertion and condensation procedure. In order to synthesize E-2-phenyl-4-[α-arylethylidene]-5 (4H)- oxazolones 4E hydrogen bromide isomerization in dry benzene was used.

 Related Synthetic Route

~41%

Learn More

~20%

Detail Learn More

~16%

Learn More

~51%

Detail Learn More

~0%

Learn More

~%

Learn More

~17%

Detail Learn More

~47%

Learn More

~48%

Detail Learn More

~85%

Learn More

~0%

Learn More

~%

Learn More

~%

Learn More

~%

Learn More

~36%

Learn More

~30%

Detail Learn More