Analytical Chemistry

Isomer-specific separation of 2, 3, 7, 8-substituted polychlorinated dibenzo-p-dioxins by high-resolution gas chromatography/mass spectrometry

HR Buser, C Rappe

Index: Buser, Hans Rudolf; Rappe, Christoffer Analytical Chemistry, 1984 , vol. 56, # 3 p. 442 - 448

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Citation Number: 108

Abstract

All poiychlorlnated dlbenzo-p-dioxln (PCDD) Isomers containing four and more chlorine substituents were prepared by mlcropyrolysls of chlorophenates. The syntheses included the preparation of all 22 tetra-, 14 penta-, 10 hexa-, 2 hepta-, and octachiorinated species (tetra-to octa-CDD). The gas chromatographlc and mass spectrometrlc properties of these Isomers were studled. Hlgh-resoiutlon gas chromatography (HRGC) on a 55-m Sllar 1Oc ...

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