Macromolecules

Poly (glycidyl amine) and copolymers with glycidol and glycidyl amine repeating units: synthesis and characterization

J Meyer, H Keul, M Möller

Index: Meyer, Joerg; Keul, Helmut; Moeller, Martin Macromolecules, 2011 , vol. 44, # 11 p. 4082 - 4091

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Citation Number: 22

Abstract

The synthesis and characterization of poly (glycidol-co-glycidyl amine), poly (glycidol)-block- poly (glycidyl amine), and poly (glycidol) end-capped with a glycidyl amine unit is reported. Copolymerization of ethoxyethyl glycidyl ether with epichlorohydrin using tetraoctylammonium bromide/triisobutylaluminium as catalyst leads to statistical or block copolymers. Sequential addition of the monomers to the initiator leads to block ...