Tetrahedron letters

Transition-metal complex catalyzed polyfluoroalkylation. I. Facile addition of polyfluoroalkyl halides to carbon-carbon multiple bonds

T Fuchikami, I Ojima

Index: Fuchikami, Takamasa; Ojima, Iwao Tetrahedron Letters, 1984 , vol. 25, # 3 p. 303 - 306

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Citation Number: 97

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Addition of polyfluoroalkyl halides to alkynes and alkenes bearing a variety of substituents is effected by the catalysis of iron, cobalt and ruthenium carbonyl complexes to give the corresponding adducts in good to excellent yields under mild conditions. ... Satisfactory analytical and ...

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18146-00-4

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perfluoropropyl iodide Structure

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perfluoropropyl...

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(4,4,5,5,6,6,6-heptafluoro-2-iodohexoxy)-trimethylsilane Structure

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3,3-Diethoxy-1-propene Structure

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perfluoropropyl...

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6,6-diethoxy-1,1,1,2,2,3,3-heptafluoro-5-iodohexane Structure

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6,6-diethoxy-1,...

perfluoropropyl iodide Structure

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perfluoropropyl...

Bis(trimethylsilyl)acetylene Structure

14630-40-1

Bis(trimethylsi...

~58%

(3,3,4,4,5,5,5-heptafluoro-1-iodo-1-trimethylsilylpent-1-en-2-yl)-trimethylsilane Structure

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(3,3,4,4,5,5,5-...

(E)-3,3,4,4,5,5-heptafluoro-2-[(iodomethyl)dimethylsilyl]-1-(trimethylsilyl)pentene Structure

81388-42-3

(E)-3,3,4,4,5,5...

Perfluorooctyl iodide Structure

507-63-1

Perfluorooctyl ...

Vinyl fluoride Structure

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Vinyl fluoride

~14%

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,10-octadecafluoro-10-iododecane Structure

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1,1,1,2,2,3,3,4...

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,10,12-Nonadecafluoro-12-iodo-dodecane Structure

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1,1,1,2,2,3,3,4...

carbon monoxide Structure

201230-82-2

carbon monoxide

5,5,6,6,7,7,7-heptafluoro-3-iodohept-3-en-1-ol Structure

89608-31-1

5,5,6,6,7,7,7-h...

~89%

3-(2,2,3,3,4,4,4-heptafluorobutylidene)oxolan-2-one Structure

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3-(2,2,3,3,4,4,...

perfluoropropyl iodide Structure

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perfluoropropyl...

Vinyltrimethylsilane Structure

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Vinyltrimethylsilane

~95%

(3,3,4,4,5,5,5-heptafluoro-1-iodopentyl)-trimethylsilane Structure

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Iodotrifluoromethane Structure

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trimethyl-(3,3,3-trifluoro-1-iodopropyl)silane Structure

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trimethyl-(3,3,...

1-bromo-2-iodotetrafluoroethane Structure

421-70-5

1-bromo-2-iodot...

Vinyltrimethylsilane Structure

754-05-2

Vinyltrimethylsilane

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(4-bromo-3,3,4,4-tetrafluoro-1-iodobutyl)-trimethylsilane Structure

89608-33-3

(4-bromo-3,3,4,...

1-chloro-2-iodo-1,1,2-trifluoroethane Structure

354-26-7

1-chloro-2-iodo...

Vinyltrimethylsilane Structure

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(4-chloro-3,4,4-trifluoro-1-iodobutyl)-trimethylsilane Structure

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1,2-Dibromo-1-chloro-1,2,2-trifluoroethane Structure

354-51-8

1,2-Dibromo-1-c...

Vinyltrimethylsilane Structure

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(1,4-dibromo-3-chloro-3,4,4-trifluorobutyl)-trimethylsilane Structure

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(1,4-dibromo-3-...

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592-41-6

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~80%

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89608-37-7

1,1,1-Trifluoro...


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