e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Chemical Communications

Synthesis of 1, 1′-binaphthyls by photo-dehydro-Diels–Alder reactions

P Wessig, G Müller

Index: Wessig, Pablo; Mueller, Gunnar Chemical Communications, 2006 , # 43 p. 4524 - 4526

Full Text: HTML

Citation Number: 15

Abstract

Biaryls play an important role in numerous areas of chemistry. The biaryl structure is wide-spread across many classes of natural products, and many of them have interesting biological activities. 1 Furthermore, compounds with biaryl moieties have found broad application as catalysts in asymmetric synthesis. This is based on the often hindered rotation around the aryl–aryl single bond and the atropisomerism resulting from this. 1,1′-Binaphthyls, especially, have ...

1-(2-methoxynaphthalen-1-yl)-7-phenylhepta-1,6-diyn-3-ol Structure

1-(2-methoxynap...

~52%

1-(2-methoxynaphthalen-1-yl)-7-phenylhepta-1,6-diyn-3-one Structure

1-(2-methoxynap...

8-naphthalen-1-yl-1-phenylocta-1,7-diyn-3-ol Structure

8-naphthalen-1-...

~60%

8-naphthalen-1-yl-1-phenylocta-1,7-diyn-3-one Structure

8-naphthalen-1-...

3-naphthalen-1-ylprop-2-ynyl 3-phenylprop-2-ynoate Structure

3-naphthalen-1-...

~36%

N/A Structure

4-naphthalen-1-yl-3H-benzo[f][2]benzofuran-1-one Structure

4-naphthalen-1-...

3-(2-methoxynaphthalen-1-yl)prop-2-ynyl 3-phenylpropiolate Structure

3-(2-methoxynap...

~44%

4-(2-methoxynaphthalen-1-yl)-3H-benzo[f][2]benzofuran-1-one Structure

4-(2-methoxynap...

3-phenylprop-2-ynyl 3-(2-methoxynaphthalen-1-yl)propiolate Structure

3-phenylprop-2-...

~37%

4-(2-methoxynaphthalen-1-yl)-1H-benzo[f][2]benzofuran-3-one Structure

4-(2-methoxynap...

4-naphthalen-1-ylbut-3-ynyl 3-phenylprop-2-ynoate Structure

4-naphthalen-1-...

~40%

N/A Structure

5-naphthalen-1-yl-3,4-dihydrobenzo[g]isochromen-1-one Structure

5-naphthalen-1-...

1-Iodo-2-methoxynaphthalene Structure

1-Iodo-2-methox...

Propargyl alcohol Structure

Propargyl alcohol

~37%

3-(2-methoxynaphthalen-1-yl)prop-2-yn-1-ol Structure

3-(2-methoxynap...

1-Iodo-2-methoxynaphthalene Structure

1-Iodo-2-methox...

3-Butyn-1-ol Structure

~39%

4-(2-methoxynaphthalen-1-yl)but-3-yn-1-ol Structure

4-(2-methoxynap...

4-phenylbut-3-ynyl 3-naphthalen-1-ylprop-2-ynoate Structure

4-phenylbut-3-y...

~35%

10-naphthalen-1-yl-3,4-dihydrobenzo[g]isochromen-1-one Structure

10-naphthalen-1...

N/A Structure

1-ethynyl-2-methoxynaphthalene Structure

1-ethynyl-2-met...

~%

3-(2-methoxynaphthalen-1-yl)prop-2-ynoic acid Structure

3-(2-methoxynap...

3-(1-NAPHTHYL)-2-PROPYN-1-OL Structure

3-(1-NAPHTHYL)-...

3-Phenylpropiolic acid Structure

3-Phenylpropiol...

~93%

3-naphthalen-1-ylprop-2-ynyl 3-phenylprop-2-ynoate Structure

3-naphthalen-1-...

3-Phenylpropiolic acid Structure

3-Phenylpropiol...

4-naphthalen-1-ylbut-3-yn-1-ol Structure

4-naphthalen-1-...

~98%

4-naphthalen-1-ylbut-3-ynyl 3-phenylprop-2-ynoate Structure

4-naphthalen-1-...

1-(2-methoxynaphthalen-1-yl)-7-phenylhepta-1,6-diyn-3-one Structure

1-(2-methoxynap...

~18%

4-(2-methoxynaphthalen-1-yl)-1,2-dihydrocyclopenta[b]naphthalen-3-one Structure

4-(2-methoxynap...

8-naphthalen-1-yl-1-phenylocta-1,7-diyn-3-one Structure

8-naphthalen-1-...

~18%

7-phenyl-10,11-dihydro-9H-benzo[a]anthracen-8-one Structure

7-phenyl-10,11-...

10-naphthalen-1-yl-3,4-dihydro-2H-anthracen-1-one Structure

10-naphthalen-1...

8-naphthalen-1-yl-1-phenylocta-1,7-diyn-3-one Structure

8-naphthalen-1-...

~12%

7-phenyl-10,11-dihydro-9H-benzo[a]anthracen-8-one Structure

7-phenyl-10,11-...

10-naphthalen-1-yl-3,4-dihydro-2H-anthracen-1-one Structure

10-naphthalen-1...

phosgene Structure

4-PHENYL-3-BUTYN-1-OL Structure

4-PHENYL-3-BUTY...

~%

4-phenylbut-3-ynyl carbonochloridate Structure

4-phenylbut-3-y...

1-Ethynylnaphthalene Structure

1-Ethynylnaphthalene

4-phenylbut-3-ynyl carbonochloridate Structure

4-phenylbut-3-y...

~%

4-phenylbut-3-ynyl 3-naphthalen-1-ylprop-2-ynoate Structure

4-phenylbut-3-y...

4-PHENYL-3-BUTYN-1-OL Structure

4-PHENYL-3-BUTY...

3-Phenylpropiolic acid Structure

3-Phenylpropiol...

~87%

4-phenylbut-3-ynyl 3-phenylprop-2-ynoate Structure

4-phenylbut-3-y...

1-ethynyl-2-methoxynaphthalene Structure

1-ethynyl-2-met...

5-phenylpent-4-ynal Structure

5-phenylpent-4-ynal

~%

1-(2-methoxynaphthalen-1-yl)-7-phenylhepta-1,6-diyn-3-ol Structure

1-(2-methoxynap...