Ingold-Fischer “Persistent Radical Effect”, Solvent Effect, and Metal Salt Oxidation of Carbon-Centered Radicals in the Synthesis of Mixed Peroxides from tert-Butyl …

…, HR Bjørsvik, F Fontana, L Liguori…

Index: Bravo, Anna; Bjorsvik, Hans-Rene; Fontana, Francesca; Liguori, Lucia; Minisci, Francesco Journal of Organic Chemistry, 1997 , vol. 62, # 12 p. 3849 - 3857

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Citation Number: 65

Abstract

Mixed peroxides are formed from tert-butyl hydroperoxide (TBH), tert-butyl peroxalate (TBP), and a variety of substrates (p-cresol, cyclohexene, styrene, α-methylstyrene, acrylonitrile, 2- methylcyclohexanone). Also, the oxidation of THF in the presence of acrylonitrile under the same conditions gives the mixed peroxide, generated by addition of the tetrahydrofuranyl radical to the double bond and the cross-coupling of the radical adduct with the tert- ...