Synthèse et polymérisation de monomères fluorés acryliques substitués en position α. Partie III. Synthèse et polymérisation de l'α-heptadécafluoro- …

JM Bessière, B Boutevin, A El Bachiri…

Index: Bessiere, J. M.; Boutevin, B.; El Bachiri, A.; El Harfi, A. Journal of Fluorine Chemistry, 1993 , vol. 65, # 1-2 p. 91 - 96

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Abstract

Abstract The synthesis of ethyl α-heptadecafluoro-undecanoyloxyacrylate (3), H 2 C C (O CO CH 2 CH 2 C 8 F 17) CO 2 CH 2 CH 3, has been performed in three steps starting from ethyl bromopyruvate and heptadecafluoro-undecanoic acid, with an overall yield of c. 70%. The homopolymerization and copolymerization of 3 have been easily carried out. From the kinetic study of homopolymerization and copolymerization of monomer 3 with styrene, kp ...