The chemistry of polycyclic arene imines. I. Substitution at the nitrogen atom of 1a, 9b??dihydro??1H??phenanthro [9, 10??b] azirine

M Weitzberg, Z Aizenshtat…

Index: Weitzberg, Moshe; Aizenshtat, Zeev; Blum, Jochanan Journal of Heterocyclic Chemistry, 1981 , vol. 18, p. 1513 - 1516

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Citation Number: 13

Abstract

Abstract Chlorides of carboxylic, sulfonic and phosphoric acids proved to convert phenanthrene-9, 10-imine into the corresponding rearranged acet-sulfon-and phosphonamidophenanthrene. Trimethylchlorosilane and N, O-bis (trimethylsilyl) acetamide reacted with the imine without destruction of the aziridine ring. The silylated compound could be transferred into the respective N-substituted phenanthrene-9, 10-imines when treated ...