Reductive cleavage of the halogen-phosphorus, oxygen-phosphorus and phosphorus-phosphorus bonds with alkali metals

J Nycz, J Rachon

Index: Phosphorus, Sulfur and Silicon and Related Elements, , vol. 161, p. 39 - 59

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Citation Number: 11

Abstract

... reaction mixture: pyrophosphonates 4, pyrophosphites 2 as well as the phosphorous phosphoric anhydrides 3 ... anion 19 and phosphino radical 20 (path- way b). Both phosphorus radicals can ... of potassium naphthalenide in THF, then into this reaction mixture sulfur and methyl ...