Indium??Catalyzed Reductive Esterification of a Carboxylic Acid: Sequential Preparation of an Ester and Symmetrical Ether

…, Y Usui, R Ikeda, T Konakahara

Index: Sakai, Norio; Usui, Yuta; Ikeda, Reiko; Konakahara, Takeo Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3397 - 3401

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Citation Number: 22

Abstract

Abstract An unprecedented reductive dimerization of two carboxylic acids to produce ester derivatives by a combination catalyst involving InBr 3 and sulfuric acid is described. A sequential conversion of the in-situ formed ester to a symmetrical ether by indium-catalyzed deoxygenation of the ester with a hydrosilane in the same pot was also demonstrated.